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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
09 January 2017 - 13 January 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
Commission Regulation (EC) No 440/2008 of 30 May 2008
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
250 °C
Atm. press.:
>= 100 - <= 101 kPa

Results of the auto-ignition temperature determination are shown in the following table:

Temperature (ºC)

Clean Flask (Yes/No)

Volume (µL)

Ignition Delay (s)

Observations

200

Yes

70

>300

No ignition, grey fumes emitted

250

Yes

70

>300

No ignition, grey fumes emitted

300

Yes

70

7

Orange flame, grey fumes emitted

290

No

70

9

Orange flame, grey fumes emitted

280

No

70

16

Orange flame, grey fumes emitted

270

No

70

12

Orange flame, grey fumes emitted

260

No

70

>300

No ignition, grey fumes emitted

264

No

70

27

Orange flame, grey fumes emitted

262

Yes

70

>300

No ignition, grey fumes emitted

262

Yes

200

25

Orange flame, grey fumes emitted

260

Yes

200

19

Orange flame, grey fumes emitted

258

Yes

200

24

Orange flame, grey fumes emitted

256

Yes

200

46

Orange flame, grey fumes emitted

254

Yes

200

29

Orange flame, grey fumes emitted

252

Yes

200

>300

No ignition, grey fumes emitted

252

Yes

400

>300

No ignition, grey fumes emitted

252

Yes

600

>300

No ignition, grey fumes emitted

252

Yes

800

55

Orange flame, grey fumes emitted

250

Yes

800

>300

No ignition, grey fumes emitted

250

Yes

1000

>300

No ignition, grey fumes emitted

250

Yes

1200

>300

No ignition, grey fumes emitted

250

Yes

1400

59

Orange flame, grey fumes emitted

248

Yes

1400

>300

No ignition, grey fumes emitted

248

Yes

1600

>300

No ignition, grey fumes emitted

248

Yes

1800

>300

No ignition, grey fumes emitted

248

Yes

2000

>300

No ignition, grey fumes emitted

248

Yes

2200

>300

No ignition, grey fumes emitted

Room temperature: 21 to 22°C
Atmospheric pressure: 100 to 101 kPa
Observed result: 250 °C

Conclusions:
The auto-ignition temperature of the test substance has been determined to be 250 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases), in compliance with GLP.
Executive summary:

The auto-ignition temperature of the test substance has been determined to be 250 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Description of key information

The auto-ignition temperature of the test substance has been determined to be 250 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
250 °C

Additional information