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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Phototransformation in air

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Administrative data

Endpoint:
phototransformation in air
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Study cited in peer reviewed and generally accepted database.

Data source

Referenceopen allclose all

Reference Type:
secondary source
Title:
Kinetics and mechanisms of the gas-phase reactions of hydroxyl radical with organic compounds
Author:
Atkinson R
Year:
1989
Bibliographic source:
J Phys Chem Ref Data, Monograph 1: 135
Reference Type:
publication
Title:
A kinetics investigation of the gas-phase reactions of OH radicals with cyclic ketones and diones: mechanistlc insights.
Author:
Dagaut P et al.
Year:
1988
Bibliographic source:
J Phys Chem 92: 4375-4377.

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
Measured, study was performed according to Wallington (1987). Wallington TJ, Kurylo MJ (1987). J Phys Chem, 91: 5050.
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Cyclohexanone
EC Number:
203-631-1
EC Name:
Cyclohexanone
Cas Number:
108-94-1
Molecular formula:
C6H10O
IUPAC Name:
Cyclohexanone

Study design

Details on test conditions:
Sensitiser (for indirect photolysis): OH
Sensitiser concentration: 0.5E6 molecule/cm³
Duration of test at given test condition
Temp.:
25 °C

Results and discussion

Dissipation half-life of parent compound
DT50:
2.5 d
Transformation products:
no

Any other information on results incl. tables

The rate constant by 25 °C = 6.39 (+/- 0.51)*10E-12 cm3/molecule*sec.

Rate constant (for indirect photolysis): = 0.00000000000639 cm³/(molecule*sec)
Degradation in % (for indirect photolysis): = 50 after 2.5 day(s)

Applicant's summary and conclusion