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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Hydrolysis

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Administrative data

Link to relevant study record(s)

Description of key information

No data

Key value for chemical safety assessment

Additional information

According to Annex XI of regulation (EC) 1907/2006, testing for a specific endpoint may be omitted if testing does not appear to be scientifically necessary or if it is technically not possible to conduct the study as a consequence of the properties of the substance. Under REACH (ECHA 2017, Chapter R.7B – Endpoint Specific Guidance), the term ‘Hydrolysis’ refers to the “Decomposition or degradation of a chemical by reaction with water”, and this as a function of pH (i.e., abiotic degradation). In the case of inorganic substances, like vanadylhydrogenphosphate-hemihydrate (CAS no. 93280-40-1), the chemical safety assessment is generally based on total elemental metal concentrations, regardless of their (pH-dependent) speciation in the environment. Therefore, physicochemical processes like degradation or transformation by reaction with water are judged not relevant. Depending on the prevailing environmental conditions, formation of different V-species may occur, but the chemical assessment will not make any differentiation among the different V-species. This total, elemental-based assessment (pooling all speciation forms together) can be considered as a worst-case assumption for the chemical assessment. In conclusion, (abiotic) degradation is an irrelevant process for inorganic substances that are assessed on an elemental basis.