3H-1,2,4-Triazol-3-one, 2,4-dihydro-4-methyl-5-propoxy-

Guidance on Safe Use

First-aid measures

4.1 Description of first aid measures

General advice

Move out of dangerous area. Remove contaminated clothing immediately and dispose of safely. Place and transport victim in stable position (lying sideways).

Inhalation

Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.

Skin contact

Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms

Headache, Daze, Unconsciousness, Aspiration may cause pulmonary oedema and pneumonitis., Symptoms and hazards refer to the solvent.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment

Treat symptomatically. Gastric lavage is not normally required. However, if a significant amount (more than a mouthful) has been ingested, administer activated charcoal and sodium sulphate.

Fire-fighting measures

5.1 Extinguishing media

Suitable

Water spray, Carbon dioxide (CO2), Foam, Sand

5.2 Special hazards arising from the substance or mixture

In the event of fire the following may be released:, Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), Nitrogen oxides (NOx)

5.3 Advice for firefighters

Special protective equipment for fire-fighters

In the event of fire, wear self-contained breathing apparatus.

Further information

Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Precautions

Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment.

6.2 Environmental precautions

Do not allow to get into surface water, drains and ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up

Clean contaminated floors and objects thoroughly, observing environmental regulations. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).  Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

7.1 Precautions for safe handling

Advice on safe handling

Use only in area provided with appropriate exhaust ventilation.

Advice on protection against fire and explosion

Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.

Hygiene measures

Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt). Wash hands before breaks and immediately after handling the product.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

Store in a place accessible by authorized persons only. Keep containers tightly closed in a dry, cool and well-ventilated place.

Advice on common storage

Keep away from food, drink and animal feedingstuffs.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN 1307

Shipping information

Proper shipping name and description:

XYLENES

Chemical name:

XYLENES

Language:

English

Labels:

Packaging: 3
Bulk: 3
Haz ID: 30
EAC: 3Y

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN 1307

Shipping information

Proper shipping name and description:

XYLENES

Chemical name:

XYLENES

Language:

English

Labels:

Packaging: 3
Bulk: 3
Haz ID: 30

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN 1307

Shipping information

Proper shipping name and description:

XYLENES

Chemical name:

XYLENES

Labels:

Packaging: 3
Bulk: 3

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN 1307

Shipping information

Proper shipping name and description:

XYLENES

Chemical name:

XYLENES

Labels:

Packaging: 3

Remarks

SpecialProvisions

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with  REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).  Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.  

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.

Exposure controls

Respiratory protection

If product is handled while not enclosed, and if contact may occur:

Wear respirator with an organic vapours and gas filter mask (protection factor 10) conforming to EN140 type A or equivalent.

Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.

Hand protection

Fluorinated rubber gloves

Glove thickness

0,4 mm

Eye protection

Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).

Skin and body protection

Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.

Wear standard coveralls and Category 3 Type 4 suit.

Stability and reactivity

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity

not applicable

Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.

Dispose in accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.