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Physical & Chemical properties

Water solubility

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Reference
Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Experimental Phase: 17 December 1999 to 09 May 2000. Report Issued: 05 July 2000.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.6 (Water Solubility)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
flask method
Key result
Water solubility:
ca. 0.5 g/L
Conc. based on:
test mat.
Temp.:
20 °C
pH:
> 4 - < 6
Key result
Water solubility:
< 0.003 g/L
Conc. based on:
test mat.
Temp.:
20 °C
pH:
> 6 - < 6.3
Remarks on result:
other: pH 6 to 6.3 was ambient pH
Key result
Water solubility:
< 0 g/L
Conc. based on:
test mat.
Temp.:
20 °C
pH:
> 8 - < 10

Results from the Preliminary Tests

Preliminary test result at pH range 4 to 6

The preliminary estimate of water solubility was 0.491g/l.

 

Preliminary test result at ambient pH

The preliminary estimate of water solubility was 1.07 x 10-2g/l.

 

Preliminary test result at pH range 8 to 10

The preliminary estimate of water solubility was <1.53 x 10-3g/l.

Conclusions:
The water solubility of Tribasic Copper Sulphate at 20 ± 0.5 °C was determined to be:

At pH 4 to 6 = 0.5 g/l
At pH 6 to 6.3 (ambient pH) = <0.00342 g/l
At pH 8 to 10 = <0.000255 g/l
Executive summary:

Introduction

The determination was carried out using Method A6 of Commission Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).

Method

Water solubility at a pH 4 to 6, ambient pH (6 to 6.3) and pH 8 to 10 was assessed using the flask shake method.

Results and Conclusion

The water solubility of Tribasic Copper Sulphate at 20 ± 0.5 °C  was determined to be:

At pH 4 to 6 = 0.5 g/l

At pH 6 to 6.3 (ambient pH) = < 0.0032 g/l

At pH 8 to 10 =  <0.000255 g/l

Description of key information

The water solubility of Tribasic Copper Sulphate at 20 ± 0.5 °C was determined to be <0.00342 g/l at pH 6 to 6.3.

Key value for chemical safety assessment

Water solubility:
0.003 g/L
at the temperature of:
20 °C

Additional information

The water solubility of the test substance at 20 ± 0.5 °C  was determined to be:

At pH 4 to 6 = 0.5 g/l

At pH 6 to 6.3 (ambient pH) = < 0.0032 g/l

At pH 8 to 10 =  <0.000255 g/l