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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Description of key information

Dry calcium carbide is not highly flammable under the test conditions of test method EU A.10.

However, upon contact with water the test substance is instantly degraded to calcium hydroxide and the extremely flammable gas acetylene.

Key value for chemical safety assessment

Flammability:
substances and mixtures which in contact with water emit flammable gases

Additional information

In a test according to method EU A.10 it could be demonstrated that dry calcium carbide is not highly flammable.

However, the intrinsic physico-chemical hazard profile is determined by the release of the extremely flammable gas acetylene from calcium carbide upon contact with water. As no standard test data (e.g. according to method EU A.12) are available, a search for publically available information has been conducted to identify relevant information for calcium carbide regarding the endpoint flammability. This information as well as data from an internal test report of the lead registrant regarding the release of the highly flammable gas acetylene from calcium carbide upon contact with water were subject to expert review.

It could be demonstrated that the formation rate of acetylene gas from calcium carbide upon contact with water at ambient temperatures was > 10 L/(kg min). Thus, calcium carbide can be classified as Water-react. 1.

Justification for classification or non-classification

In a test according to method EU A.10 it could be demonstrated that dry calcium carbide is not highly flammable.

Peer reviewed handbook data show that the formation rate of acetylene gas from calcium carbide upon contact with water at ambient temperatures was > 10 L/(kg min). Thus, calcium carbide can be classified as Water-react. 1.