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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
March 16, 1998 - March 27, 1998
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Justification for type of information:
Study conducted under GLP and in a trusted laboratory.
Guideline:
EU Method A.14 (Explosive properties)
Principles of method if other than guideline:
Method: Koenen test as described in EC Guideline A14.
GLP compliance:
yes
Key result
Test series:
UN Test series 1
Method:
UN Test 1 (b): Koenen test
Parameter:
limiting load (N)
Value:
360
Result:
negative, no explosion

Table 1 Thermal Stability, Koenen test results








































Nozzle DiameterReaction Initiation afterResults
2 mm100 secNo fragments, cartridge unchanged
2 mm97 secNo fragments, cartridge unchanged
2 mm98 secNo fragments, cartridge unchanged
6 mm95 secNo fragments, cartridge unchanged
6 mm93 secNo fragments, cartridge unchanged
6 mm95 secNo fragments, cartridge unchanged

 


Table 2. Mechanical Sensitivity, Drop-Weight Test results








































MassDrop HeightResults
10 kg40 cmNegative, no optical change in product apparent
10 kg40 cmNegative, no optical change in product apparent
10 kg40 cmNegative, no optical change in product apparent
10 kg40 cmNegative, no optical change in product apparent
10 kg40 cmNegative, no optical change in product apparent
10 kg40 cmNegative, no optical change in product apparent

 


Mechanical Sensitivity (Friction Mill)
Method : BAM friction mill as described in EC Guideline A 14
Pin pressure : 360 N
Result : Six times negative

Interpretation of results:
GHS criteria not met
Conclusions:
Spirodiclofen is not explosive when heated under defined confinement not sensitive to shock and to friction
Executive summary:

Spirodiclofen is not explosive when heated under defined confinement, not sensitive to shock and to friction when tested according to EC Guideline A 14.

Description of key information

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification