Registration Dossier
Registration Dossier
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EC number: 616-441-2 | CAS number: 77168-63-9
Guidance on Safe Use
Administrative data
First-aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Most important symptoms and effects, both acute and delayed:
May cause sensitisation by skin contact.
Contact with the eyes may produce redness.
Indication of any immediate medical attention and special treatment needed:
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment:
Treat symptomatically.
Fire-fighting measures
Suitable extinguishing media: water spray, carbon dioxide (CO2), foam and dry powder.
Extinguishing media which must not be used for safety reasons: direct water jet.
Special hazards arising from the substance or mixture:
Do not inhale explosion and combustion gases.
Products of combustion include carbon monoxide (CO), carbon dioxide (CO2), sulphur oxides (SOx) and oxides of nitrogen (NOx).
Advice for firefighters:
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
Keep containers cool with water spray.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Wear personal protection equipment.
Remove all sources of ignition.
Provide adequate ventilation.
Use appropriate respiratory protection.
Remove persons to safety.
See protective measures under "Handling and storage" and "Exposure controls/personal protection".
Environmental precautions:
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand.
Methods and material for containment and cleaning up:
Wash with plenty of water.
Reference to other sections:
See also section "Exposure controls/personal protection" and "Disposal considerations".
Handling and storage
Precautions for safe handling:
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there are not incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section "Exposure controls/personal protection" for recommended protective equipment.
Conditions for safe storage, including any incompatibilities:
Store in a cool, dry place. Store in a tightly closed container.
Ventilate where the product is stored and manipulated.
Keep material away from heat, sparks, static electricity and flames.
Keep away from food, drink and feed.
Incompatible materials: oxidizing agents and acids
Instructions as regards storage premises:
Adequately ventilated premises.
Specific end use(s)
None in particular.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
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Marine transport (UN RTDG/IMDG)
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
Shipping information
- Proper shipping name and description:
- Not classified as dangerous in the meaning of transport regulations.
- Chemical name:
- 4-(Pyridin-4-yl)-1,3-thiazole-2(3H)-thione
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not classified as dangerous in the meaning of transport regulations.
Shipping information
- Proper shipping name and description:
- Not classified as dangerous in the meaning of transport regulations.
- Chemical name:
- 4-(Pyridin-4-yl)-1,3-thiazole-2(3H)-thione
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Exposure controls / personal protection
Control parameters:
No occupational exposure limit available
DNEL Exposure Limit Values: not available
PNEC Exposure Limit Values: not available
Exposure controls
Eye protection: safety glasses with side protection for chemicals (EN166).
Protection for skin: overall.
Protection for hands: use protective gloves according to EN 374 standards, on the base of the intended use (penetration and permeation).Suitable material: NBR (nitrile rubber).
Respiratory protection: particle filter device (DIN EN 143) with filter "P", white colour.
Thermal Hazards: none
Environmental exposure controls: do not allow uncontrolled leakage of product into the environment.
Appropriate engineering controls: none.
Stability and reactivity
Reactivity: stable under normal conditions.
Chemical stability: the product is stable at normal handling- and storage conditions.
Possibility of hazardous reactions: the product is stable at normal handling- and storage conditions.
Conditions to avoid: avoid humidity. Keep material away from heat, sparks, flames, static electricity.
Incompatible materials: oxidizing agents and acids.
Hazardous decomposition products: products of combustion include carbon monoxide (CO) and carbon dioxide (CO2).
In the event of fire produces oxides of nitrogen NOx.
Disposal considerations
Waste treatment methods: recover if possible. In so doing, comply with the local and national regulations currently in force.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
