Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Boiling point

Currently viewing:

Administrative data

Link to relevant study record(s)

Referenceopen allclose all

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2009-09-21
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Test procedure in accordance with national standard methods (ASTM) without GLP.
Qualifier:
according to guideline
Guideline:
other: ASTM-D1120 Standard Test Method for Boiling Point of Engine Coolants
Deviations:
not specified
GLP compliance:
no
Type of method:
differential scanning calorimetry
Boiling pt.:
319 °C
Atm. press.:
101.3 kPa
Decomposition:
no
Remarks on result:
other: Equilibrium boiling point (corrected)

Measurements:

(repeat determination)

 Observed boiling point  606.0 °F  610.0 °F
 Barometric pressure  762 mm Hg  775 mm Hg
 Equilibrium boiling point (corrected)  606.0 °F  608.5 °F
Conclusions:
Boiling point of Hexadecan-1-ol: 607 °F (319 °C) at 760 mmHg (mean value of 2 determinations)
Executive summary:

The boiling point of Hexadecan-1 -ol was tested according to ASTM-D1120 Standard Test Method for Boiling Point of Engine Coolants, the derived value was 607 °F (319 °C), corrected to atmospheric pressure.

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Value obtained from a recognised source of physico-chemical data.
Principles of method if other than guideline:
No details are available on the guideline used to determine this result.
GLP compliance:
not specified
Boiling pt.:
334 °C
Atm. press.:
other: see Remarks
Remarks on result:
other: The exact atmospheric pressure at which this result was determined is not stated, but may be assumed to be within the normal range of standard pressure.
Boiling pt.:
334 - 344 °C
Atm. press.:
other: see Remarks
Remarks on result:
other: The exact atmospheric pressure at which this result was determined is not stated, but may be assumed to be within the normal range of standard pressure. This value is taken from an older edition of the Handbook (1990).
Conclusions:
A boiling point value of 334ºC is reported in a handbook of reliable data which has been subject to peer-review and in which the original data sources are traceable. The result is considered to be reliable.

Description of key information

The boiling point of hexadecan-1-ol is 319°C.

Key value for chemical safety assessment

Additional information

The boiling point of 319°C was determined in a reliable study.

It is supported by a value of 334°C taken from a reliable handbook.

Discussion of trends in the Category of C6-24 linear and essentially-linear aliphatic alcohols:

As chain length increases,boiling point increases. This is because molecular weight is higher and intermolecular forces in the substance are all higher.There is some evidence for decomposition before boiling for the longest chain alcohols in this group.