Registration Dossier
Registration Dossier
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EC number: 212-110-8 | CAS number: 763-32-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
DO NOT DELAY!
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
DO NOT DELAY!
Rinse opened eye for several minutes under running water. Then consult a doctor.
Check for and remove any contact lenses.
· After swallowing:
DO NOT DELAY!
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
If vomiting occurs spontaneously, keep head below hips to prevent aspiration.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor: Treat symptomatically and supportively.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
DO NOT DELAY!
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
DO NOT DELAY!
Rinse opened eye for several minutes under running water. Then consult a doctor.
Check for and remove any contact lenses.
· After swallowing:
DO NOT DELAY!
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
If vomiting occurs spontaneously, keep head below hips to prevent aspiration.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor: Treat symptomatically and supportively.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
Flammable. The vapour mixes well with air.
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
Soluble in water.
Volatile.
· 5.3 Advice for firefighters
· Protective equipment:
Wear fully protective suit.
Wear self-contained respiratory protective device.
Do not inhale explosion gases or combustion gases.
· Additional information Cool endangered receptacles with water spray
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
Flammable. The vapour mixes well with air.
Vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
Soluble in water.
Volatile.
· 5.3 Advice for firefighters
· Protective equipment:
Wear fully protective suit.
Wear self-contained respiratory protective device.
Do not inhale explosion gases or combustion gases.
· Additional information Cool endangered receptacles with water spray
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep ignition sources away - no smoking.
· 6.2 Environmental precautions:
Do not allow to penetrate the ground/soil.
Do not allow product to reach sewage system or any water course in the undiluted form.
· 6.3 Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep ignition sources away - no smoking.
· 6.2 Environmental precautions:
Do not allow to penetrate the ground/soil.
Do not allow product to reach sewage system or any water course in the undiluted form.
· 6.3 Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.
Handling and storage
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Keep away from heat and direct sunlight.
Welding and other hot work operations in the work area must only be permitted under supervision.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Use a closed system, ventilation, and explosion-proof electrical equipment.
Ignition temperature: 345 °C
Temperature class: T2
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Prevent any seepage into the ground.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Further information about storage conditions:
Store in a bunded area.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.
Storage temperature : 15 - 25 °C
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Keep away from heat and direct sunlight.
Welding and other hot work operations in the work area must only be permitted under supervision.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Use a closed system, ventilation, and explosion-proof electrical equipment.
Ignition temperature: 345 °C
Temperature class: T2
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Prevent any seepage into the ground.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Further information about storage conditions:
Store in a bunded area.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.
Storage temperature : 15 - 25 °C
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN1987
Shipping information
- Proper shipping name and description:
- ALCOHOLS, N.O.S. (3-methylbut-3-en-1-ol)
- Chemical name:
- (3-methylbut-3-en-1-ol
- Labels:
- 3
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1987
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1987
Shipping information
- Proper shipping name and description:
- ALCOHOLS, N.O.S. (3-methylbut-3-en-1-ol)
- Chemical name:
- 3-methylbut-3-en-1-ol
- Labels:
- 3
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1987
Shipping information
- Proper shipping name and description:
- ALCOHOLS, N.O.S. (3-methylbut-3-en-1-ol)
- Chemical name:
- 3-methylbut-3-en-1-ol
- Labels:
- 3
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.2 Exposure controls
· Personal protective equipment:
Select PPE appropriate for the operations taking place taking into account the product properties.
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Do not eat, drink, smoke or sniff while working.
A safe system of work must be formulated and followed to ensure safe working with this product. Relevant
workers must receive suitable and sufficient training and supervision.
Ensure that eyewash stations and safety showers are close to the workstation location.
· Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
If respiratory protection is required, institute a complete respiratory protection program including selection, fit
testing, training, maintenance and inspection.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
· Body protection:
Solvent resistant protective clothing
Body protection must be chosen depending on product properties, activity and possible exp
· Personal protective equipment:
Select PPE appropriate for the operations taking place taking into account the product properties.
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Do not eat, drink, smoke or sniff while working.
A safe system of work must be formulated and followed to ensure safe working with this product. Relevant
workers must receive suitable and sufficient training and supervision.
Ensure that eyewash stations and safety showers are close to the workstation location.
· Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
If respiratory protection is required, institute a complete respiratory protection program including selection, fit
testing, training, maintenance and inspection.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
· Body protection:
Solvent resistant protective clothing
Body protection must be chosen depending on product properties, activity and possible exp
Stability and reactivity
10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
Flammable. The vapour mixes well with air.
Above 40°C explosive vapour/air mixtures may be formed.
Vapours may form explosive mixtures with air.
Ignitable vapour/air mixture possible if heated above flashpoint and/or when nebulising/spraying.
· 10.3 Possibility of hazardous reactions
Reacts violently with strong oxidants causing fire and explosion hazard.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Strong oxidising agents.
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
Flammable. The vapour mixes well with air.
Above 40°C explosive vapour/air mixtures may be formed.
Vapours may form explosive mixtures with air.
Ignitable vapour/air mixture possible if heated above flashpoint and/or when nebulising/spraying.
· 10.3 Possibility of hazardous reactions
Reacts violently with strong oxidants causing fire and explosion hazard.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Strong oxidising agents.
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide
Disposal considerations
13.1 Waste treatment methods
· Recommendation
Recommended Hierarchy of Controls:
- Minimise waste;
- Reuse if not contaminated;
- Recycle, if possible; or
- Safe disposal (if all else fails).
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
Used, degraded or contaminated product may be classified as hazardous waste. Anyone classifying hazardous
waste and determining its fate must be qualified in accordance with state and international legislation.
· European waste catalogue
Waste key numbers in accordance with the European Waste Catalogue (EWC) are origin-referred defined.
Since this product is used in several industries, no waste key can be provided by the supplier. The waste key
number should be determined in arrangement with your waste disposal partner or the responsible authority.
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Container remains hazardous when empty. Continue to observe all precuations.
Containers, even those that are “empty,” may contain residues that can develop flammable and/or hazardous
vapours upon heating. Do not cut, drill, grind, weld, or perform similar operations on or near empty
containers.
· Recommendation
Recommended Hierarchy of Controls:
- Minimise waste;
- Reuse if not contaminated;
- Recycle, if possible; or
- Safe disposal (if all else fails).
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Contact waste processors for recycling information.
Used, degraded or contaminated product may be classified as hazardous waste. Anyone classifying hazardous
waste and determining its fate must be qualified in accordance with state and international legislation.
· European waste catalogue
Waste key numbers in accordance with the European Waste Catalogue (EWC) are origin-referred defined.
Since this product is used in several industries, no waste key can be provided by the supplier. The waste key
number should be determined in arrangement with your waste disposal partner or the responsible authority.
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Container remains hazardous when empty. Continue to observe all precuations.
Containers, even those that are “empty,” may contain residues that can develop flammable and/or hazardous
vapours upon heating. Do not cut, drill, grind, weld, or perform similar operations on or near empty
containers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
