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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

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Administrative data

Endpoint:
flammable liquids: obsolete as covered by section 'Flash point'
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
the study does not need to be conducted because the substance is a liquid
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
data waiving: supporting information
Reference
Endpoint:
flash point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
12 May 1999
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
closed cup
Flash point apparatus:
Setaflash apparatus
Key result
Flash point:
182 °C
Atm. press.:
100.49 kPa

Table 1: Results

Temperature (°C)

Observations

20

No flash

25

No flash

30

No flash

35

No flash

40

No flash

45

No flash

50

No flash

55

No flash

60

No flash

65

No flash

70

No flash

70 (fresh sample)

No flash

75

No flash

80

No flash

85

No flash

90

No flash

95

No flash

100

No flash

105

No flash

110

No flash

115 (fresh sample)

No flash

120

No flash

125

No flash

130

No flash

135

No flash

140

No flash

145

No flash

150

No flash

155

No flash

160

No flash

165

No flash

165 (fresh sample)

No flash

170

No flash

175

No flash

180

No flash

185

A blue flash spread across the sample cup

180 (fresh sample)

No flash

181

No flash

182

A blue flash spread across the sample cup

182 (fresh sample)

A blue flash spread across the sample cup

182 (fresh sample)

A blue flash spread across the sample cup

180 (fresh sample)

No flash

180 (fresh sample)

No flash

 

Interpretation of results:
GHS criteria not met
Conclusions:
The flash point of the test material was determined to be 182 ± 2 °C
Executive summary:

The flash point of the test material was determined in a study which was conducted under GLP conditions and in accordance with the standardised guideline EU Method A.9, using the closed-cup method.

Under the conditions of the study, the flash point of the test material was found to be 182 °C at atmospheric pressure.

Reason / purpose for cross-reference:
data waiving: supporting information
Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
31 March 1999 to 4 June 1999
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
differential scanning calorimetry
Boiling pt.:
> 360 °C
Atm. press.:
99.73 kPa
Decomposition:
no

The appearance of the test material in the crucibles after conducting the DSC determinations was the same as the test material at the start of the test (brown liquid) - this indicates no decomposition had occurred.

No phase transition occurred.

A calculated value of boiling temperature using an adapted Stein and Brown method gave the boiling temperature to be 773 K (500 °C).

Conclusions:
The boiling point of the test material was determined to be in excess of 633 ± 0.5 K at 99.73 kPa.
Executive summary:

The boiling point of the test material was evaluated in a study which was conducted under GLP conditions and in accordance with the standardised guideline EU Method A.2 using Differential Scanning Calorimetry.

The boiling point of the substance was determined to be in excess of 633 ± 0.5 K at 99.73 kPa.

Data source

Materials and methods

Results and discussion

Applicant's summary and conclusion