Registration Dossier
Registration Dossier
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EC number: 214-154-3 | CAS number: 1100-88-5
Guidance on Safe Use
Administrative data
First-aid measures
First aid measures
Description of first aid measures
In case of inhalation
- IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
- Immediate medical attention is required.
In case of skin contact
- Wash with plenty of soap and water.
- Consult a physician.
In case of eye contact
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- Seek medical advice.
In case of ingestion
- If accidentally swallowed obtain immediate medical attention.
Most important symptoms and effects, both acute and delayed
In case of inhalation
Effects
- Fatal if inhaled.
- Mechanical irritation from the particulates generated by the product.
In case of skin contact
Effects
- May cause skin irritation.
- Redness
In case of eye contact
Effects
- Causes serious eye damage.
Symptoms
- Irritation
- Redness
- Lachrymation
- Pain
In case of ingestion
Effects
- Fatal if swallowed.
Symptoms
- Suffocation
- Vomiting
- Abdominal pain
- Nausea
Indication of any immediate medical attention and special treatment needed
Notes to physician
- None
Fire-fighting measures
Extinguishing media
Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Unsuitable extinguishing media
- None
Special hazards arising from the substance or mixture
Specific hazards during firefighting
- The product is not flammable.
- Not explosive
- In use, may form flammable/explosive vapour-air mixture.
- Take measures to prevent the build up of electrostatic charge.
- Hazardous decomposition products formed under fire conditions.
Hazardous combustion products: - Carbon oxides - Phosphorus compounds
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.
Accidental release measures
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ensure adequate ventilation.
- Avoid dust formation.
- Material can create slippery conditions.
- Sweep up to prevent slipping hazard.
- Keep away from open flames, hot surfaces and sources of ignition.
- Refer to protective measures listed in sections 7 and 8.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up
- Pick up and arrange disposal without creating dust.
- Do not create a powder cloud by using a brush or compressed air.
- Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local regulations (see section 13).
Reference to other sections
- Refer to protective measures listed in sections 7 and 8 of SDS
Handling and storage
Precautions for safe handling
- Ensure adequate ventilation.
- Avoid dust formation.
- Avoid inhalation, ingestion and contact with skin and eyes.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
- To avoid thermal decomposition, do not overheat.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep in properly labelled containers.
- Keep away from heat and sources of ignition.
- Keep away from combustible material.
- Keep away from incompatible products
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
Packaging material
Suitable material
- Plastic materials.
Specific end use(s)
- Contact your supplier for additional information
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3464
Shipping information
- Proper shipping name and description:
- ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. (Benzyltriphenylphosphonium Chloride)
- Labels:
- 6.1
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3464
Shipping information
- Proper shipping name and description:
- ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. (Benzyltriphenylphosphonium Chloride)
- Labels:
- 6.1
Special provisions / remarks
- Remarks:
- Special precautions for user
Hazard Identification Number: 60
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3464
Shipping information
- Proper shipping name and description:
- ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. (Benzyltriphenylphosphonium Chloride)
- Labels:
- 6.1
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3464
Shipping information
- Proper shipping name and description:
- ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. (Benzyltriphenylphosphonium Chloride)
- Labels:
- 6.1
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- Special precautions for user
Packing instruction (cargo aircraft) 676
Max net qty/pkg 100.00 kg
Packing instruction (passenger aircraft) 669
Max net qty/pkg 25.00 kg
Exposure controls / personal protection
Control measures
Engineering measures
-Provide appropriate exhaust ventilation at machinery and at places where dust can be generated.
-Provide local ventilation appropriate to the product decomposition risk (see section 10).
-Refer to protective measures listed in sections 7 and 8.
-Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
-In case of insufficient ventilation, wear suitable respiratory equipment.
-In case of dust clouds, dust mask type P3.
-In case of decomposition (see section 10), use an air breathing apparatus with face mask.
-Use only respiratory protection that conforms to international/ national standards.
Hand protection
-Wear protective gloves.
Suitable material
-Nitrile rubber
-Neoprene gloves
-Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
-Tightly fitting safety goggles
Skin and body protection
-Wear work overall and safety shoes.
Hygiene measures
-Ensure that eyewash stations and safety showers are close to the workstation location.
-When using do not eat, drink or smoke.
-Wash hands before breaks and at the end of workday.
-Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
-Dispose of rinse water in accordance with local and national regulations.
Stability and reactivity
Reactivity
- No dangerous reaction known under conditions of normal use.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- Under certain conditions, small dust-particles from the product may form flammable and explosive mixtures with the air.
10.4 Conditions to avoid
- To avoid thermal decomposition, do not overheat.
- Keep away from flames and sparks.
Incompatible materials
- Strong bases
- Alkali metals
- alkaline hydroxides
Hazardous decomposition products - Carbon oxides - Phosphorus compounds- The release of other hazardous decomposition products is possible.
Disposal considerations
Waste treatment methods
Product Disposal
- If recycling is not practicable, dispose of in compliance with local regulations.
Advice on cleaning and disposal of packaging
- Dispose of contents/ container to an approved landfill.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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