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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Reference
Endpoint:
explosive properties of explosives
Type of information:
other: Expert statement
Adequacy of study:
key study
Study period:
Study completion date - 11 July 2006.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Expert statement
Qualifier:
no guideline followed
Principles of method if other than guideline:
The explosive properties of FAT 40827/A were estimated based on the UN Recommendations on the Transport of Dangerous Goods (Manual of Tests and Criteria, Annex 6, Orange Book, 3rd edition, 1999) where a set of criteria is compiled to identify materials being potential explosives
GLP compliance:
no
Specific details on test material used for the study:
Name: FAT 40827/A
Parameter:
other: Determination of the exothermic decomposition energy
Remarks on result:
other: The presence of azo groups and unsaturated C-C linkage seems to pose no risk as demonstrated by the calorimetric test.

Based on item 3 as outlined above, FAT 40827/A is not to be classified as explosive material and no experimental determination according to the EC test guideline A.14 has to be performed.

The presence of azo groups and unsaturated C-C linkage seems to pose no risk as demonstrated by the calorimetric test.

Thus it can be concluded beyond a reasonable doubt, that FAT 40827/A is not a potential explosive and does not have a potential for rapid energy release. Nevertheless, this  judgement is in respect to classification; it does not necessarily mean that any processing hazards can be discounted.

Interpretation of results:
GHS criteria not met
Conclusions:
FAT 40827/A is not a potential explosive and does not have a potential for rapid energy release. Nevertheless, this  judgement is in respect to classification; it does not necessarily mean that any processing hazards can be discounted.
Executive summary:

The explosive properties of FAT 40827/A were estimated based on the UN Recommendations on the Transport of Dangerous Goods (Manual of Tests and Criteria, Annex 6, Orange Book, 3rd edition, 1999) where a set of criteria is compiled to identify materials being potential explosives.

Based on item 3 as outlined above, FAT 40827/A is not to be classified as explosive material and no experimental determination according to the EC test guideline A.14 has to be performed.

The presence of azo groups and unsaturated C-C linkage seems to pose no risk as demonstrated by the calorimetric test.

Thus, it can be concluded beyond a reasonable doubt, that FAT 40827/A is not a potential explosive and does not have a potential for rapid energy release. Nevertheless, this  judgement is in respect to classification; it does not necessarily mean that any processing hazards can be discounted.

Description of key information

FAT 40827/A is not classified as explosive material.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

The explosive properties of FAT 40827/A were estimated based on the UN Recommendations on the Transport of Dangerous Goods (Manual of Tests and Criteria, Annex 6, Orange Book, 3rd edition, 1999) where a set of criteria is compiled to identify materials being potential explosives. Based on item 3 as outlined above, FAT 40827/A is not to be classified as explosive material and no experimental determination according to the EC test guideline A.14 has to be performed. The presence of azo groups and unsaturated C-C linkage seems to pose no risk as demonstrated by the calorimetric test. Thus, it can be concluded beyond a reasonable doubt, that FAT 40827/A is not a potential explosive and does not have a potential for rapid energy release. Nevertheless, this  judgement is in respect to classification; it does not necessarily mean that any processing hazards can be discounted.

Justification for classification or non-classification

Based on expert judgement built on chemical structure assessment and handling experience, the substance is not subject to classification for explosivity according to CLP (Regulation EC No 1272/2008)