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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
09 Mar - 11 Mar 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
no
Type of method:
effusion method: Knudsen cell
Specific details on test material used for the study:
Storage conditions: ambient temperature (10 – 30 °C), dry
Temp.:
ca. 50 °C
Vapour pressure:
ca. 0.001 hPa
Temp.:
ca. 25 °C
Vapour pressure:
ca. 0 hPa
Temp.:
ca. 20 °C
Vapour pressure:
ca. 0 hPa

Results
Vapour pressure was measured in the range of 30 to 60 °C.
Table 1 – Measured vapour pressures and corresponding temperatures

Temperature [°C]

Vapour pressure [hPa]

30

6.6E-05

35

1.1E-04

40

1.9E-04

45

3.3E-04

50

5.4E-04

55

8.8E-04

60

1.4E-03

 

The vapour pressure values for 20, 25 and 50 °C were calculated using the Antoine equation and the constants shown below.
A = 10.56675
B = -4471.82
C = 273.15

Table 2 – Vapour pressure values extrapolated from experimental data

T [°C]

p [hPa]

p [Pa]

20

2.1E-05

2.1E-03

25

3.7E-05

3.7E-03

50

5.4E-04

5.4E-02

Description of key information

2.1E-05 hPa at 20 °C
3.7E-05 hPa at 25 °C

5.4E-04 hPa at 50 °C

(OECD 104, estimated using Antoine equation)

Key value for chemical safety assessment

Vapour pressure:
0.002 Pa
at the temperature of:
20 °C

Additional information

The vapour pressure values for the test item were extrapolated from the experimental data.