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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

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Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15 September 2015 - 19 January 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.5: Recommendations on the Transport of Dangerous Goods, Part III, Test N.4: “Test Method for Self-Heating Substances" (2009)
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
p-fluorophenyl 4-piperidyl ketone hydrochloride
EC Number:
247-070-0
EC Name:
p-fluorophenyl 4-piperidyl ketone hydrochloride
Cas Number:
25519-78-2
Molecular formula:
C12H14FNO.ClH
IUPAC Name:
4-(4-fluorobenzoyl)piperidine hydrochloride
Test material form:
solid: particulate/powder

Results and discussion

Relative self-ignition temperature (solids)
Key result
Remarks on result:
no self-ignition observed up to the melting point

Any other information on results incl. tables

Preliminary test (EC A.16)


A strong exothermic effect of the test item was observed above the melting point. The temperature of the test item reached 400°C at an oven temperature of 392°C. It demonstrated that the self-ignition temperature of the test item is 392°C.


After the experiment, the test item had turned into a black/brown residue and was partially collected in a container that was placed below the cube. It indicated that the test item had molten, decomposed and/or reacted during the experiment.


 


Main test (UN N.4)


A negative result was obtained during the main test according to the UN N.4 method. No spontaneous ignition occurred and no exothermic effect of the test item was observed. It demonstrated that the test item is “not a self-heating substance”. According to the UN guideline, no further testing is required.


After the experiment, the test item had turned into an off-white residue. It indicated that the test item had decomposed and/or reacted during the experiment

Applicant's summary and conclusion

Conclusions:
Based on the results of the UN N.4 test performed, the test item is considered ‘not self-heating’.