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Diss Factsheets

Physical & Chemical properties

Boiling point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 21/01/2013 to 04/02/2013
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Remarks:
The study was conducted according to an internationally recognised method, and under GLP. Substance ID is adequately specified with purity. Validation applies, with minor restrictions due to heating rate.
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Deviations:
yes
Remarks:
heating rate slightly exceed maximum of 1K/min as recommended
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
yes
Remarks:
heating rate slightly exceed maximum of 1K/min as recommended
GLP compliance:
yes (incl. QA statement)
Remarks:
signed on 12 March 2012
Type of method:
method according to Siwoloboff
Boiling pt.:
233 °C
Atm. press.:
97 kPa
Decomposition:
no
Remarks on result:
other: =506 K; measured; accuracy +/-2K
Key result
Boiling pt.:
235 °C
Atm. press.:
101.325 kPa
Remarks on result:
other: corrected to normal atmP

STAGE OF TEST TEMPERATURE (K)
PRELIMINARY TEST DETERMINATION 1 DETERMINATION 2
Beginning of measurement 311 475 487
Bubbles were emerged from the capillary 514 505 507
Atmospheric pressure (kPa) 97.0 97.0 97.0
Executive summary:

The boiling point of the test substance was determined under GLP according to OECD 103/EU A2 guideline, Siwoloboff (capillary) method.

Two main runs were performed, and the mean value was corrected to normal Patm.

Measured boiling point = 233°C under 97.0 kPa; Corrected boiling point = 235°C to normal Patm

Description of key information

Measured boiling point = 233°C under 97.0 kPa; Corrected boiling point = 235°C to normal Patm

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
235 °C

Additional information

A reliable experimental study, conducted according to a recognized OECD/EC method and under GLP, is available. Despite minor restriction due to heating rate, it is considered as a key study. The result is retained as key data.