Cyclohexyldimethoxymethylsilane

Guidance on Safe Use

First-aid measures

Description of first aid measures

Take off all contaminated clothing immediately.

Inhalation

If aerosol or mists are formed:

Move victims into fresh air.

In case of persistent discomfort: Consult doctor immediately.

Skin contact

Wash off immediately with plenty of water.

Consult a doctor in the event of permanent skin irritation.

Eye contact

Keeping eyelid open, immediately rinse thoroughly for at least 5 minutes using plenty of water or, if necessary, eye rinsing solution.

Consult an ophthalmologist.

Ingestion

Have the mouth rinsed with water.

Only when patient fully conscious:

Have patient drink plenty of water in small sips.

Consult a physician immediately.

Most important symptoms and effects, both acute and delayed

Symptoms

After absorbing large amounts of substance:

Liberation of reaction products (Methanol) can lead to symptoms of poisoning.

Possible signs of poisoning:

daze, dizziness, nausea, colicky abdominal pain, respiratory disturbance.

Symptoms upon increasing intoxication: dysopia, loss of eyesight.

Indication of any immediate medical attention and special treatment needed

If required, therapy of irritative effect.

Treatment:

Early endoscopy in order to assess mucosa lesions in the oesophagus and stomach which may appear. If necessary, aspirate leftover substance.

Detection of substance (Methanol) possible in:

Blood

Antidote treatment: ethanol.

Fire-fighting measures

Suitable extinguishing media

foam, CO2, dry powder

Special hazards arising from the substance or mixture

Formation of flammable or explosive vapour/air mixtures possible.

Special protective equipment for fire-fighters

In the case of fire, wear respiratory protective equipment independent of surrounding air and chemical protective suit.

Advice for firefighters

Use water spray to cool unopened containers.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Do not inhale vapours / aerosols.

Wear personal protective equipment; see section 8.

Environmental precautions

Do not allow entrance in sewage water, soil stretches of water, groundwater, drainage systems.

Methods and material for containment and cleaning up

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Fill into marked, sealable containers.

To be disposed of in compliance with existing regulations.

Suitable binder:       sand (for damming up), sawdust, universal absorbent

Handling and storage

Handling

Precautions for safe handling

Provide sufficient ventilation and exhaust at the workplace.

Advice on protection against fire and explosion

Take precautionary measures against static discharges.

Keep away from sources of ignition - No smoking.

Water used to extinguish fire should not enter drainage systems, soil or stretches of water.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Storage

Conditions for safe storage, including any incompatibilities

Keep containers tightly closed in a cool, well-ventilated place.

Protect from moisture.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3082

Shipping

Labels:

ADR/RID-Labels
9

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3082

Shipping

Labels:

ADR/RID-Labels
9

Special provisions / remarks

Remarks:

Environmentally Hazardous

Marine transport (UN RTDG/IMDG)

UN number:

3082

Shipping information

Proper shipping name and description:

Proper technical name (Proper shipping name)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (cyclohexyldimethoxymethylsilane)

Chemical name:

cyclohexyldimethoxymethylsilane

Marine pollutant

Special provisions / remarks

Remarks:

Environmentally Hazardous

Air transport (UN RTDG/ICAO/IATA)

UN number:

3082

Shipping information

Proper shipping name and description:

Proper technical name (Proper shipping name)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (cyclohexyldimethoxymethylsilane)

Chemical name:

cyclohexyldimethoxymethylsilane

Special provisions / remarks

Remarks:

Environmentally Hazardous

Additional transport information

Additional information

Special provisions / remarks / other:

orange warning plate: 90 / 3082
Tunnel Restriction Code: (ADR)(E)
Loading instructions/Remarks
IATA_C: ERG-Code 9L
IATA_P: ERG-Code 9L

Exposure controls / personal protection

Control parameters

Engineering measures

Ensure suitable suction/aeration at the work place and with operationalmachinery.Local ventilation if necessary.

Personal protective equipment

Respiratory protection

In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:

use respiratory equipment with suitable filter or wear a self contained respiratory apparatus

Hand protection

Glove material       for example, Fluorinated rubber (Viton)

Material thickness       0,4 mm

Break through time       >= 480 min

Selection of protective gloves to meet the requirements of specific workplaces.

Suitability for specific workplaces should be clarified with protective glove manufacturers.

The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.

Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).

Eye protection

safety glasses

Skin and body protection

Wear suitable protective clothing.

Hygiene measures

Do not inhale vapours from hot product.

Avoid contact with skin and eyes.

Remove immediately all contaminated clothing.

Smoking, eating and drinking should be prohibited in the application area.

Cleanse and apply cream to skin after work.

Protective measures

The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).

It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.

If the workplace threshold limit value is exceeded and/or the substance is released (dust), use appropriate respiratory protection

Do not breathe in vapours or aerosols.

If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.

Avoid contact with skin, eyes and clothing.

Stability and reactivity

Stability

Stable under normal conditions.

Conditions to avoid

Vapours can form explosive mixtures with air.

Incompatible materials

humidity

Hazardous decomposition products

Methanol in case of hydrolysis.

Disposal considerations

Product

With respect to local regulations, e.g. dispose of to suitable waste incineration plant.

Review all local, state and federal regulations concerning health and pollution for appropriate disposal procedures.

Uncleaned packaging

Packaging, that can not be reused after cleaning must be disposed or recycled in accordance with all federal, national and local regulations.

If there is product residue in the emptied container, follow directions for handling on the container's label.

Incorrect disposal or reuse of this container is illegal and can be dangerous.

Other countries: observe the national regulations.

Waste Key Number

No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.