Registration Dossier
Registration Dossier
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EC number: 252-899-6 | CAS number: 36177-92-1
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice.
SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash contaminated clothing before using them again.
INHALATION: Remove to open air. If breathing is irregular, seek medical advice.
INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an
unconscious person
SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash contaminated clothing before using them again.
INHALATION: Remove to open air. If breathing is irregular, seek medical advice.
INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an
unconscious person
Fire-fighting measures
SUITABLE EXTINGUISHING MEDIA
The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS
None in particular
The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS
None in particular
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. If there are no contraindications, spray solid products
with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there
is no hazard. Do not handle damaged containers or the leaked product before donning appropriate protective gear. For information on risks
for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, see the other sections of this
sheet.
Environmental precautions:
The product must not penetrate the sewers, surface water, ground water and neighbouring areas.
Methods and material for containment and cleaning up:
Use inert absorbent material (sand, vermiculite, diatomeous earth, Kieselguhr, etc.) to soak up leaked product. Collect the majority of the
remaining material and deposit it in containers for disposal. If there are no contraindications, use jets of water to eliminate product residues.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. If there are no contraindications, spray solid products
with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there
is no hazard. Do not handle damaged containers or the leaked product before donning appropriate protective gear. For information on risks
for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, see the other sections of this
sheet.
Environmental precautions:
The product must not penetrate the sewers, surface water, ground water and neighbouring areas.
Methods and material for containment and cleaning up:
Use inert absorbent material (sand, vermiculite, diatomeous earth, Kieselguhr, etc.) to soak up leaked product. Collect the majority of the
remaining material and deposit it in containers for disposal. If there are no contraindications, use jets of water to eliminate product residues.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
Handling and storage
Precautions for safe handling:
Do not smoke while handling and use.
Conditions for safe storage, including any incompatibilities:
Store in a well ventilated place, keep far away from sources of heat, bright flames and sparks and other sources of ignition.
Specific end use(s):
Information not available.
Do not smoke while handling and use.
Conditions for safe storage, including any incompatibilities:
Store in a well ventilated place, keep far away from sources of heat, bright flames and sparks and other sources of ignition.
Specific end use(s):
Information not available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2735
Shippingopen allclose all
SpecialProvisionsopen allclose all
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.
- Labels:
- 8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product below the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details during use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipment must comply with the rules in force indicated below.
HAND PROTECTION
Protect hands with category II (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in PVC, neoprene, nitryl or
equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove
resistance to preparations should be checked before use, as it can be unpredictable. Gloves’ limit depends on the duration of exposure.
EYE PROTECTION
Wear protective airtight goggles (ref. standard EN 166).
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with
soap and water after removing overalls.
RESPIRATORY PROTECTION
If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction
established by the company’s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2 or 3) of
which must be chosen according to the limit concentration of use (ref. standard EN 141).
The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of
technical measures limiting worker exposure. The protection provided by masks is in any case limited.
If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency,
or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained,
open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half
mask or mouthpiece (ref. standard EN 138).
In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent
accidental absorption.
HAND PROTECTION
Protect hands with category II (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in PVC, neoprene, nitryl or
equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove
resistance to preparations should be checked before use, as it can be unpredictable. Gloves’ limit depends on the duration of exposure.
EYE PROTECTION
Wear protective airtight goggles (ref. standard EN 166).
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard EN 344). Wash body with
soap and water after removing overalls.
RESPIRATORY PROTECTION
If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction
established by the company’s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2 or 3) of
which must be chosen according to the limit concentration of use (ref. standard EN 141).
The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of
technical measures limiting worker exposure. The protection provided by masks is in any case limited.
If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency,
or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained,
open-circuit compressed air breathing apparatus (ref. standard EN 137) or fresh air hose breathing apparatus for use with full face mask, half
mask or mouthpiece (ref. standard EN 138).
In the presence of risks of exposure to splashes or squirts during work, adequate mouth, nose and eye protection should be used to prevent
accidental absorption.
Stability and reactivity
Reactivity:
There are no particular risks of reaction with other substances in normal conditions of use.
Chemical stability:
The product is stable in normal conditions of use and storage.
Possibility of hazardous reactions:
The vapours may also form explosive mixtures with the air.
Conditions to avoid:
Avoid overheating, electrostatic discharge and all sources of ignition.
Incompatible materials:
Information not available.
Hazardous decomposition products:
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
There are no particular risks of reaction with other substances in normal conditions of use.
Chemical stability:
The product is stable in normal conditions of use and storage.
Possibility of hazardous reactions:
The vapours may also form explosive mixtures with the air.
Conditions to avoid:
Avoid overheating, electrostatic discharge and all sources of ignition.
Incompatible materials:
Information not available.
Hazardous decomposition products:
In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released.
Disposal considerations
Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product
should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
Waste transportation may be subject to ADR restrictions.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product
should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
Waste transportation may be subject to ADR restrictions.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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