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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1995-03-21 to 1995-04-21
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
The experimental procedure used complied with that specified in Method A15 of Commission Directive 92/69/EEC (which constitutes Annex V of Council Directive 67/548/EEC).
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
256 °C
Atm. press.:
>= 100.1 - <= 103.69 kPa

Results

The results detailed below were obtained during testing.

Test temperature (°C)

Test volume (µL)

Ignition delay (S)

Observations

50

70

>300

No ignition occurred

100

70

>300

No ignition occurred

150

70

>300

No ignition occurred

200

70

>300

No ignition occurred. Grey vapour was emitted.

250

70

>300

No ignition occurred. Grey vapour was emitted.

300 (clean flask)

70

1

The sample ignited with an orange/blue flame. Grey vapour was emitted.

280 (clean flask)

70

5

The sample ignited with an orange/blue flame. Grey vapour was emitted.

270 (clean flask)

70

19

The sample ignited with an orange/blue flame. Grey vapour was emitted.

260 (clean flask)

70

91

The sample ignited with a large orange flame. Grey vapour was emitted.

256 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

258 (clean flask)

70

96

The sample ignited with a large orange flame. Grey vapour was emitted.

256 (clean flask)

70

226

The sample ignited with a large orange flame. Grey vapour was emitted.

250 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

254 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

254 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

254 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

254 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

254 (clean flask)

70

>300

No ignition occurred. Grey vapour was emitted.

 

Room temperature

19 to 22 °C

Atmospheric pressure

100.1 -103.69 kPa

 

Conclusion

The test substance has been determined to have an auto-ignition temperature of 256 ± 5°C.

Reference

Anon (1987), Electrical Apparatus for Explosive Gas Atmospheres. Part 4: Method of Test for Ignition Temperature. IEC Publications 79-4, P1-19.

Conclusions:
3-(Trimethoxysilyl)propyl acrylate was determined to have an auto-ignition temperature of 256 ± 5°C at 100.1-103.69 kPa using a relevant test method. The result is considered to be reliable.

Description of key information

Auto-ignition temperature: 256 ± 5°C at 100.1-103.69 kPa (EU Method A.15)

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
256 °C

Additional information

An auto-ignition temperature value of 256 ± 5°C at 100.1-103.69 kPa was determined for the substance using a relevant test method and in compliance with GLP. The result is considered to be reliable.