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Physical & Chemical properties

Flash point

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
27 June 2019 to 10 September 2019
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
1992
Deviations:
no
Qualifier:
according to guideline
Guideline:
ASTM D93 (Standard test methods for flash point by pensky-martens closed cup tester)
Version / remarks:
2013
Deviations:
no
GLP compliance:
yes
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
88.1 °C
Atm. press.:
101.325 kPa

RESULTS AND DISCUSSION

- For the flash point determinations, instrument performance was verified through the use of a

dodecane reference standard; the reference substance provided acceptable results (see Table 1, attached).

- Results of the observed and corrected flashpoint determinations for the test substance are presented in Tables 3 and 4 (attached).

- The mean measured corrected flashpoint of the test substance was determined to be 88.1 °C (n = 2, % difference = 2.42).

- The test substance native colour (light yellow) did not change during the flash point testing.

Interpretation of results:
GHS criteria not met
Conclusions:
The mean measured flashpoint, when corrected to one atmosphere pressure (101.325 kPa) of the test substance was determined to be 88.1 °C (% difference = 2.42) or 361.3 K (% difference = 0.59).
Executive summary:

GUIDELINE

The investigation was performed in accordance with Council of the European Communities(1992) EU Directive 92/69/EEC, Method A.9 "Flash-Point" and American Society for Testing and Materials(2013) D 93-13 "Flashpoint by Pensky-Martens Closed Cup Tester".

 

METHODS

The flashpoint of the test substance was determined using the Pensky-Martens closed cup test method. The flashpoint measures the tendency of a substance to form a flammable mixture with air. In the Pensky-Martens method, the test substance is heated in a cup protected from the atmosphere at a constant rate with continual stirring. A device capable of ignition is periodically directed at the cup. The flashpoint is the lowest temperature, corrected to a pressure of one atmosphere (760 mm or 101.325 kPa), at which the vapor above the sample is ignited.

 

RESULTS

The mean measured flashpoint, when corrected to one atmosphere pressure (101.325 kPa) of the test substance was determined to be 88.1 °C (% difference = 2.42) or 361.3 K (% difference = 0.59).

Description of key information

The mean measured flashpoint, when corrected to one atmosphere pressure (101.325 kPa) of the test substance was determined to be 88.1 °C (% difference = 2.42) or 361.3 K (% difference = 0.59) (EU Method A.9 and ASTM D 93-13).

Key value for chemical safety assessment

Additional information

GUIDELINE

The investigation was performed in accordance with Council of the European Communities(1992) EU Directive 92/69/EEC, Method A.9 "Flash-Point" and American Society for Testing and Materials(2013) D 93-13 "Flashpoint by Pensky-Martens Closed Cup Tester".

 

METHODS

The flashpoint of the test substance was determined using the Pensky-Martens closed cup test method. The flashpoint measures the tendency of a substance to form a flammable mixture with air. In the Pensky-Martens method, the test substance is heated in a cup protected from the atmosphere at a constant rate with continual stirring. A device capable of ignition is periodically directed at the cup. The flashpoint is the lowest temperature, corrected to a pressure of one atmosphere (760 mm or 101.325 kPa), at which the vapor above the sample is ignited.

 

RESULTS

The mean measured flashpoint, when corrected to one atmosphere pressure (101.325 kPa) of the test substance was determined to be 88.1 °C (% difference = 2.42) or 361.3 K (% difference = 0.59).