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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Link to relevant study record(s)

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Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
October 2009
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Comparable to guideline study (OECD113) with acceptable restrictions
Qualifier:
no guideline available
Principles of method if other than guideline:
The thermal stability of a substance was determined using Difference Scanning Calorimetry (DSC). Therefore, some milligrams of the substance were weighed into a glass crucible which was fused by an oxyhydrogen flame.
GLP compliance:
no
Specific details on test material used for the study:
Manufactured by the Subimitter,
Batch number B 526734
Purity > 95%
Test substance thermally stable:
no
Key result
Operating temp.:
> 25 - < 400 °C
Sublimation:
not determined
Transformation products:
not measured

The differential scanning calorimetry in a closed glass crucible showed a plausible decomposition signal in the temperature range of 194.26°C - 283.71 °C with a decomposition energy of 260.83 J/g.

Conclusions:
The differential scanning calorimetry in a closed glass crucible showed a plausible decomposition signal in the temperature range of 194.26°C - 283.71 °C with a decomposition energy of 260.83 J/g.
Executive summary:

The differential scanning calorimetry in a closed glass crucible showed a plausible decomposition signal in the temperature range of 194.26°C - 283.71 °C with a decomposition energy of 260.83 J/g.

Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
15 July 2019
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Qualifier:
according to guideline
Guideline:
other: VDI 2263
Principles of method if other than guideline:
A Grewer Oven test and an 8h-long-term-stability test were performed.
GLP compliance:
not specified
Specific details on test material used for the study:
Manufactured by the Subimitter,
Batch number B 526734
Purity > 95%
Test substance thermally stable:
yes

The 8h long-term-stability temperature (LZT) was 160 °C.

Conclusions:
The temperature of onset of temperature raise in airstream was 231 °C (Peak Maximum) in the Grewer test.

The 8h+8h long-term-stability temperature (LZT) was 160 °C.
Executive summary:

The 8h long-term-stability temperature (LZT) was 160 °C.

Description of key information

The differential scanning calorimetry in a closed glass crucible showed a double decomposition peak in the temperature range of 194,26 - 283,71 °C with a decomposition energy of 260,83 J/g.


A Grewer Oven test was performed. The temperature of onset of temperature raise in airstream was 231 °C. (Peak Maximum)

Additional information

Justification for classification or non-classification

Conclusive but not sufficient for classification.