Registration Dossier
Registration Dossier
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EC number: 214-290-3 | CAS number: 1119-94-4
Guidance on Safe Use
Administrative data
First-aid measures
General advice: First aider needs to protect himself.
After inhalation: fresh air.
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one
hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.
Most important symptoms and effects, both acute and delayed: Irritant effects, Cough, depressed respiration, Shortness of breath, agitation, spasms, cardiovascular disorders, CNS disorders
Fire-fighting measures
EXTINGUISHING MEDIA:
Suitable extinguishing media: Water, Foam, Carbon dioxide (CO2), Dry powder
Unsuitable extinguishing media: For this substance/mixture no limitations of extinguishing agents are given.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
Fire may cause evolution of: hydrogen bromide, nitrogen oxides, nitrous gases
ADVICE FOR FIREFIGHTERS:
Special protective equipment for firefighters: Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information: Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Accidental release measures
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders: Protective equipment.
ENVIRONMENTAL PRECAUTIONS
Do not let product enter drains.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully. Dispose of properly. Clean up
affected area. Avoid generation of dusts.
Handling and storage
PRECAUTIONS FOR SAFE HANDLING
Advice on safe handling: Observe label precautions.
Hygiene measures: Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage conditions: Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.
Recommended storage temperature see product label.
SPECIFIC END USE(S)
Apart from the uses mentioned in section 3.5 no other specific uses are stipulated.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
EXPOSURE CONTROLS
Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.
Individual protection measures: Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye/face protection: Safety glasses
Hand protection:
full contact:
Glove material: Nitrile rubber
Glove thickness: 0,11 mm
Break through time: > 480 min
splash contact:
Glove material: Nitrile rubber
Glove thickness: 0,11 mm
Break through time: > 480 min
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Other protective equipment:
protective clothing
Respiratory protection:
required when dusts are generated. Recommended Filter type: Filter P 3 (acc. to DIN 3181) for solid and liquid
particles of toxic and very toxic substances.
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Environmental exposure controls:
Do not let product enter drains.
Stability and reactivity
REACTIVITY:
The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
CHEMICAL STABILITY:
sensitive to moisture
POSSIBILITY OF HAZARDOUS REACTIONS:
Violent reactions possible with:
Strong oxidizing agents
CONDITIONS TO AVOID:
Moisture.
INCOMPATIBLE MATERIALS:
no information available
Disposal considerations
Waste treatment methods:
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
