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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
flammability
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
1984

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: UN Recommendations on the transport of dangerous goods, manual of tests and criteria, Part III, sub-section 33.2.1 (N.1)
Principles of method if other than guideline:
UN-method and EU-method A.10 are nearly identical. The UN N.1 test, however, has an additional criteria whether a wetted zone is able to stop the fire.
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Methenamine
EC Number:
202-905-8
EC Name:
Methenamine
Cas Number:
100-97-0
Molecular formula:
C6H12N4
IUPAC Name:
1,3,5,7-tetraazatricyclo[3.3.1.1³,⁷]decane

Results and discussion

Flammable solids
Test procedure:
burning time (test type not further specified)
Remarks:
or specified in description of method (migrated information)
Burning time:
ca. 34 s
Pyrophoric solids
Test procedure:
ignition time on contact with air
Remarks:
Ignition on contact with air refers to either Pyrophoric solids or Pyrophoric liquids depending on physical state (migrated information).
Remarks on result:
no ignition on contact with air (not further specified)
Remarks:
corresponding to 'no' in migrated source record.
Pyrophoric liquids
Test procedure:
ignition time on contact with air
Remarks:
Ignition on contact with air refers to either Pyrophoric solids or Pyrophoric liquids depending on physical state (migrated information).
Remarks on result:
no ignition on contact with air (not further specified)
Remarks:
corresponding to 'no' in migrated source record.

Any other information on results incl. tables

burning level = 6: very quick combustion under flame-ocurrence

speed of combustion: 34.5 s/100 mm (average value)

Applicant's summary and conclusion

Conclusions:
With an average combustion-speed of 34.5 s/100 mm methenamine was determined to be highly flammable (combustion-speed < 45 s/100 mm).
Executive summary:

With an average combustion-speed of 34.5 s/100 mm methenamine was determined to be highly flammable (combustion-speed < 45 s/100 mm).

burning level = 6: very quick combustion under flame-ocurrence