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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
Study was conducted between 8 June and 10 June 2010
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Non-GLP, no guideline experimental investigation (an ad-hoc test accepted by the regulatory authorities).
Qualifier:
no guideline available
Principles of method if other than guideline:
Exothermic activity determination with Differential Scanning Calorimeter by heating at a constant rate (of up to 20 K.min-1) up to 500°C .
GLP compliance:
no

Test Results

The full profile for the experiment is provided in Graph 1.

The sample was not observed to undergo any significant energetic events up to 500°C.

Interpretation of results:
other: No explosive properties
Conclusions:
Ash does not have exothermic activity up to 500°C. Thus, the test material can be concluded not to have explosive properties.
Executive summary:

Thermal stability analysis of Ash was performed to support the interpretation of structural analysis, according to which there are no chemical groups associated with explosive properties. The thermal stability analysis was conducted using Differential Scanning Calorimetry (DSC). No exothermic activity was observed up to 500°C (i.e. there were no events with a magnitude of > 500 J.g-1).

Endpoint:
explosive properties of explosives
Data waiving:
other justification
Justification for data waiving:
other:

Description of key information

Based on molecular structure and thermal stability analysis, Ash does not have explosive properties.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Thermal stability analysis of Ash was performed to support the interpretation of structural analysis, according to which there are no chemical groups associated with explosive properties. The thermal stability analysis was conducted using Differential Scanning Calorimetry (DSC). No exothermic activity was observed up to 500°C (i.e. there were no events with a magnitude of > 500 J.g-1). Based on this combination of factors, it is beyond reasonable doubt that the material will not exhibit explosive properties. The conduct of the EU Method A.14 tests is therefore not considered appropriate.

Justification for classification or non-classification

Ash is an inorganic substance which does not have explosive properties indicating functional groups (OECD testing methods publication). This result along with thermal stability observed in a Differential Scanning Calorimetry analysis prove that no classification is required.