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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Endpoint:
stability: thermal, sunlight, metals, other
Remarks:
Migrated from section 'Stability: thermal, sunlight, metals'
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2014
Report date:
2014

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
Version / remarks:
Differential Scanning Calorimetry (DSC)
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Bis(hydroxylammonium) sulphate
EC Number:
233-118-8
EC Name:
Bis(hydroxylammonium) sulphate
Cas Number:
10039-54-0
Molecular formula:
H3NO.1/2H2O4S
IUPAC Name:
bis(hydroxyammonium) sulfate
Details on test material:
- Name of test material (as cited in study report): Hydroxylammonium sulphate
- Analytical purity: ca. 99-100%

Results and discussion

For thermal stability study

Test substance thermally stable:
no
Operating temperature
Operating temp.:
30 - 500 °C
Remarks on result:
other: Heating rate 2.5 K/min
Transformation products:
not measured

Any other information on results incl. tables

1st reaction:

Onset temperature ca. 180 °C

Peak temperature 193 °C

Heat release 1310 J/g

2nd reaction:

Onset temperature 300 °C

Peak temperature 326 °C

Heat release 20 J/g

3rd reaction:

Onset temperature 400 °C

Peak temperature 437 °C

Heat release 280 J/g

Result of the storage at 140°C for 24 hours and following dynamic measurement (DSC-measurement under nitrogen):

During the storage time appr. 950 J/g were released.

Applicant's summary and conclusion