Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

Emergency measure - Inhalation: Remove person to fresh air. If signs/Symptoms develop, get

medical attention.

Emergency measure - Eyes: The eyes have directly to be washed with plenty of water (at

least 15 minutes). A doctor has to be called.

Emergency measure - Skin: The skin has directly to be washed with plenty of water (at

least 15 minutes). Contaminated shoes and clothing have to

be removed and washed before next use.

Emergency measure - Ingestion: Apply 2 glasses of water.

If signs/Symptoms develop, get medical attention

Never instil something to an unconsciuos person.

Fire-fighting measures

Recommended extinguishing agent: Not flammable, use extinguishing agents according to the

surrounding fire.

Product arising from burning: Sulfur oxide, carbon monoxide, carbon dioxide, hydrogen

fluoride.

Product determined by test: N

Protective equipment: Wear inherent protection suit including helm, breathing

protection (overpressure), closed jacket and trousers, arm,

waist and leg protection, face mask.

Accidental release measures

Emergency measures in case of spillage: Ventilate the area with fresh air. Contain spill. For larger

spills, cover drains and build dikes to prevent entry into

sewer systems or bodies of water. Working from around the

edges of the spill inward, cover with sodium carbonate

solution. Collect as much of the spilled material as

possible.

Place in a polyethylene coated metal container approved for

transportation by appropriate authorities.

Lock the affected area for unprotected personnel.

Collect the resulting residue containing solution.

Product waste has to be carefully transferred into a

solution of sodium carbonate and calcium hydroxide. The

solution has to be neutral.

Dispose of collected material as soon as possible.

The precautionary measures recommended under 2.3.10 must be

taken.

Handling and storage

Handling: The product is only intended for industrial / professional

use.

All working methods must always be designed so that skin and

eye contact as well as exposure by inhalation are excluded.

As far as possible, closed equipment must be used during

filling, transfer and metered feeding as well as during

sampling. In the case of handling in open systems, any

vapours/aerosols that can form should be extracted directly

at the point of origin. In the case of handling in open

systems, any vapours/aerosols that can form should be

extracted directly at the point of origin. Respiratory

protec-tion (e.g. :::) should be worn in case technical

extraction or ventilation measures are not possible or are

insufficient. Even if skin contact is only possible for

short periods, tested protective gloves (e.g. :::) and

suitable protective clothing (e.g. :::) must be worn. Safe

eye protection (e.g. :::) is absolutely essential. 145

Adequate washing facilities should be available in the

immediate vicinity of the work area and eye douches should

be made available and their location indicated

conspicuously. After skin contact, the affected parts of the

skin shoud be cleaned thoroughly using (:::).

Storage: Store away from aluminium and zinc.

Store the product in a cool place, tightly closed and

protected against moisture in the original packing drum.

Ensure good room ventilation, if necessary, local exhaust

ventilation. Only release waste air to the outside air via

suitable separators or scrubbers. Maintain storage areas

according to the principles of good industrial hygiene.

Close all opened packing drums tightly again after use.

Avoid product resi-dues on the packing drums. Store the

substance in such a way that outsiders do not have access to

it. Provide for measures for the retention of product and

exting uishing water. Keep away from food, tobacco, alcohol,

acids and lyes.

Packaging of the substance and or preparation: Polyethylene canister or polyethylene can, respectively.

Transport information

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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

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Special provisions / remarks
Remarks:
Transport code: UN-Nr. 2922
Transport: Weitere Transport-Codes:


ADR/RID: Kl. 8 (6.1) Verp. Gr. II

Klassifizierungscode: CT1

Verpackungsanweisung: P001

Aetzender fluessiger Stoff, giftig, n.a.g
(Perfluorbutansulfinsaeure und

Fluorwasserstoffsaeure)

Corrosive Liquid, toxic, n.o.s.

(perfluorobutane sulfinic acid and

hydrofluoric acid)


GGVSEE/IMDG: Kl. 8 (6.1) Verp. Gr. II

EMS: F-A, S-B P.I.: P001

Corrosive liquid, toxic, n.o.s.

(perfluorobutane sulfinic acid and

hydrofluoric acid)


IATA/ICAO: Kl. 8 (6.1) Verp. Gr. II

Packing may exceed quantitiy limitations!

Corrosive Liquid, toxic, n.o.s.

(perfluorobutane sulfinic acid and

hydrofluoric acid)


Low amounts regulations:

According to column 7 of table A (list of hazardous goods)
the transport of 1l of each inner packaging and totally

30 kg as limited amount is possible. For limited amounts

in elongation- or shrinking foil packaging 1l and totally

20 kg are approved.


For the internal transportation:

Use original containers or other unbreakable and correctly
labelled containers. Keep containers tightly closed and
secure by suitable measures against falling down.
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: None.

Chemical reaction with water: No reaction.

Dust explosion: No dust explosion, perfluorobutane sulfinic acid is a

liquid.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: The product will completely react during the polymerisation.

Industry - Possibility of neutralisation: none

Industry - Possibility of destruction: controlled discharge: Physical / biological sewage handling,

exhaust air combustion,

thermal sewage handling.

Industry - Possibility of destruction - incineration: Exhaust air combustion.

Industry - Possibility of destruction - water purification: The sewage will be delivered to a physical and biological

handling apparatus.

Public at large - Possibility of recovery/recycling: The product will not arrive to a general-public area.

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