Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation :
First aid measures
Move exposed person to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention if adverse health effects persist
or are severe. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Ingestition:
Wash out mouth with water. Move exposed person to fresh air.
Keep person warm and at rest. If material has been swallowed and
the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be
dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention. Never
give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.
Skin Contact:
Wash skin immediately with plenty of water and soap. Remove
contaminated clothing and shoes. Continue to rinse for at least 10
minutes. Get medical attention. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Eye Contact:
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention.

Fire-fighting measures

Extingguishing media
Suitable extinguishing media:In case of fire ,use water spray (fog),foam, dry chemical or CO2
Unsuitable extinguishing media:None known.
Spezial hazards arising from the substance
Hazards from the substance: In a fire or if heated , a pressure increase will occur and the container may burst.
Hazardous combustion products:Decomposition products may include the following materials:carbon oxids, sulfur oxids
Advice for firefighters
Special precautions for firefighters:Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.No action shall be taken involving any personal risk or without suitable training. This materialis harmful to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Special protective equipment for fire-fighters:
Fire-fighters should wear appropriate protective equipment and self -contained breathing apparatus /SCBA) with a full face-piece operated in positive pressure mode.
Remark.Cool closed containers exposed to fire with water.

Accidental release measures

Personal precautions,protective equipment and emergency procedures:
No action shall be taken involving any persoanl risk or without suitable training. keep unnecessary and unprotected personnel from entering. Do not touch or walk Through split material. Avoid breathing vapour or mist. Provide adequate ventilation. put on appropriate personal protective equipment.

Environmental precautions: Avoid dispersal of split material and runoff and contact with soil, waterways , drains and sewers. Inform the relevant authorities if the product has caused environtal pollution(sewers,waterways , soil or air). Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Handling and storage

Precautions for safe handling:
Put on appropriate protective equipment.Eating , drinking and smoking should be prohibited in ares where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not breathe vapuor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. keep in the original container or an approved alternativemade from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.
Conditions for safe storage, including any incompatibilities:
Store in accordance with local regulations. Store in original container protected from direct sunligiht in a dry,cool and well-ventilated area,away from incompatible materials and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefullyreleased and kept upright to prevent leckage. Do not store in unlabbeled containers. Use appropriate containment to avoid environmental contamination.
remarks: Vent waste air only via suitable seperators or scrubbers. Take precautionary measures against electrostatic discharges. avoid all possible sources of ignition(spark or flame).
Recommended monitoring procederes:
If this product contains ingredients with exposure limits, personal,workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necesssity to use respiratory protective equipment. Reference should be made to European Standard EN689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Transport information

Land transport (ADR/RID)

UN number:
UN2810
Proper shipping name and description:
TOXIC LIQUID,Organic, N.O.S.
Language:
English
Classification code:
GHS 06
Packaging group:
III
Labels:
GHS 06,skull and crossbones
Special Provisions:
Special precautions for user /Additional information:
Hazardindentificationnumber 60
Limited Quanttity LQ7

Inland waterway transport (ADN(R))

UN number:
UN2810
Proper shipping name and description:
TOXIC LIQUID,Organic,N.O.s.
Language:
English
Classification code:
GHS 06
Packaging group:
III
Labels:
GHS 06
Remarks
Hazard identificaion number 60
Limited quantity LQ7

Marine transport (IMDG)

UN number:
UN2810
Proper shipping name and description:
TOXIC LiQUID ,organic,N.O.S.
Packaging group:
III
EmS code:
F-A,S-A
Labels:
GHS06,skulls and crossbones
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN2810
Proper shipping name and description:
TOXIC LiQUID ,organic,N.O.S.
Packaging group:
III
Labels:
GHS06,skulls and crossbones
Remarksopen allclose all

Additional transport information

SpecialProvisionsopen allclose all
Passenger aircraft :655: 60L
Cargo aircraft: 663 : 220L
Hazard Notes:
Slightly toxic,Irritating to the eyes, Evil smelling, Keep away from foodstuffs, acids and alkalis

Exposure controls / personal protection

Risk management measures
Occupational exposure controls
Technical measures : If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure belo any recommended or statutory limits.
Respiratory protection :Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: Full mask with type ABEK filter .
Hand protection :
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Polychloroprene - CR, Viton® or Polyvinyl chloride - PVC
Eye protection :
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Recommended: safety glasses with side-shields
Skin protection :
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product.
Recommended: Wear protective clothing.
Hygiene measures :
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emmissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Reactivity:No specific test data related to reactivity available for this product or
its ingredients.
Chemical stability:The product is stable.
Possibility of hazardous reactions:Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid :No specific data
Incompatible materials:No specific data
Hazardous decomposition products:Under normal conditions of storage and use, hazardous
decomposition products should not be produced.

Disposal considerations

Product
Methods of disposal: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
Hazardous waste:The classification of the product may meet the criteria for a
hazardous waste.
Packaging
methods of disposal:The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions:
This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.