Alkyl phosphites

Guidance on Safe Use

First-aid measures

General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.

Wash off with soap and plenty of water.

Immediate medical treatment is necessary as untreated

wounds from corrosion of the skin heal slowly and with

difficulty.

In case of burns apply cold water until pain subsides then seek medical advice.

In case of eye contact : Small amounts splashed into eyes can cause irreversible

tissue damage and blindness.

In the case of contact with eyes, rinse immediately with plenty

of water and seek medical advice.

Continue rinsing eyes during transport to hospital.

Remove contact lenses.

Protect unharmed eye.

Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty of water.

Do NOT induce vomiting.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

Take victim immediately to hospital.

Fire-fighting measures

Suitable extinguishing media : Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames

Unsuitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Combustibility : Not classified as flammable or combustible, but will combust if ignited.

Hazardous combustion products : Phosphorus oxides, Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Sulphur oxides

Protective equipment and precautions for firefighters: In the event of fire, wear self-contained breathing apparatus.

Fire Fighting Instructions : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions :

Advice for emergency responders

Ensure adequate ventilation. Use personal protective equipment. Evacuate personnel to safe areas. For personal protection see section 8.

Advice for non-emergency personnel

Avoid contact with spilled material. Do not touch or walk through spilled material. Keep people away from and upwind of spill/leak.

Environmental precautions : Prevent entry into waterways, sewers, basements or confined areas.

Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities

Methods for cleaning up : Prevent further leakage or spillage if safe to do so.

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Recover by pumping or with suitable absorbent

Report spills as required to appropriate authorities. Seek the advice of a specialist before using dispersants. Dispose of according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Material will sink to the sediment layer Remove debris in path of spill prior to oiling and remove contaminated debris from shoreline and water surface. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

Handling and storage

Avoid contact with skin and eyes.

Smoking, eating and drinking should be prohibited in the application area.

To avoid spills during handling keep bottle on a metal tray.

Dispose of rinse water in accordance with local and national regulations.

Normal measures for preventive fire protection.

Products may load from Infineum manufacturing site above the standard loading/unloading range.

Loading/unloading

temperature

: 25 °C (77 ° F) - 60 °C (140 ° F)

Viscosity @

Loading/unloading

temperature

: 6 cSt - 15 cSt

Static accumulator : This material is not a static accumulator

Nitrogen blanketing of containers is required

Keep container tightly closed in a dry and well-ventilated place.

Containers which are opened must be carefully resealed and kept upright to prevent leakage.

No decomposition if stored and applied as directed.

Storage temperature : <= 25 °C (77 ° F)

Incompatible materials and coatings : Polyethylene, Natural Rubber, butyl-rubber, Butadiene Rubber, Carbon steel

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN1760

Shipping

Labels:

8

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN1760

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, N.O.S. (Alkyl phosphites)

Labels:

8

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN1760

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, N.O.S.(Alkyl phosphites)

Labels:

8

Remarks

SpecialProvisions

Exposure controls / personal protection

Control parameters

Exposure limits for materials that can be formed when handling this product: When mists/aerosols can occur, the following are recommended: 5mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL

Limits/standards shown for guidance only. Follow applicable regulations.

Recommended monitoring procedures : This product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.

Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

DNEL

Reaction product of alkylthioalcohol and substituted phosphorus compound : no data available

PNEC

Reaction product of alkylthioalcohol and substituted phosphorus compound : Fresh water Value: 0,036 mg/l

Fresh water sediment Value: 0,128 mg/kg

Soil Value: 0,104 mg/kg

Exposure controls:

Appropriate engineering controls : No special requirements under ordinary conditions of use and with adequate ventilation.

Personal protective equipment

Respiratory protection : In the case of vapour formation use a respirator with an approved filter.

The applicable European standard can be found in EN 14605.

Hand protection

Remarks : Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Please observe the instructions

regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local

conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. When handling hot material, use heat

resistant gloves.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Eye/face protection : Eye wash bottle with pure water

Tightly fitting safety goggles

Wear face-shield and protective suit for abnormal processing problems.

The applicable European standard can be found in EN 166.

Skin and body protection : impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing. The applicable European standard can be found in EN 140, EN 137, EN 143, EN 14387.

Advice on general occupational hygiene

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.

Wash hands before breaks and at the end of workday.

Environmental exposure controls

General advice : Prevent entry into waterways, sewers, basements or confined areas.

Do not flush into surface water or sanitary sewer system.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains inform respective authorities.

Stability and reactivity

Reactivity:

No dangerous reaction known under conditions of normal use.

Chemical stability:

Stable under recommended storage conditions.

Hazardous reactions : No hazards to be specially mentioned.

Conditions to avoid : Elevated temperatures. Excessive heat.

Incompatible materials: Strong oxidizing agents

Hazardous decomposition products : No decomposition if used as directed.

Disposal considerations

Product : The product should not be allowed to enter drains, water courses or the soil.

Do not contaminate ponds, waterways or ditches with chemical or used container.

Dispose of contents/ container to an approved waste disposal plant.

Disposal recommendations based on material as supplied, Disposal must be in accordance with

applicable laws and regulations, and material characteristics at time of disposal

For the safety of persons conducting disposal, recycling or reclamation activities, refer to the

information in Section 8, Exposure control and personal protection.

Empty Container Warning (where applicable): Empty containers may contain residue and can be

dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums

should be completely drained and safely stored until appropriately reconditioned or disposed.

Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or

licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE,

CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT,

FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY

EXPLODE AND CAUSE INJURY OR DEATH.

Regulatory disposal information

European Waste Code : 13 02 XX

waste engine, gear and lubricating oils