Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Have the product container, label or Material Safety Data Sheet with you when calling poison control center or physician, or going for treatment.

Inhalation
Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or poison control centre immediately.

Skin contact
Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use.

Eye contact
In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.

Ingestion
If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting.

Most important symptoms and effects, both acute and delayed
No information available.

Indication of immediate medical attention and special treatment needed
There is no specific antidote available. Treat symptomatically.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media
Small fires: Use water spray, alcohol-resitant foam, dry chemical or carbon dioxide. Large fires: Alcohol-resistant foam.

Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture
As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section "stability and reactivity"). Exposure to decomposition products may be a hazard to health. Flash back possible over considerable distance.

Advice for firefighters
Wear full protective clothing and self-contained breathing apparatus.

Other information
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see section "Disposal Considerations"). If the product contaminates rivers and lakes or drains inform respective authorities.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Refer to protective measures listed in sections "Handling and Storage" and "Exposure controls/personal protection". Keep people away from and upwind of spill/leak. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Remove all sources of ignition. Pay attention to flashback.

Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.

Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see section "Disposal Considerations"). If the product contaminates rivers and lakes or drains inform respective authorities.

Reference to other sections
Refer to protective measures listed in sections "Handling and Storage" and "Exposure controls/personal protection". Refer to disposal considerations listed in section "Disposal Considerations".

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17 (3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18 (4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Precautions for safe handling
Avoid contact with skin and eyes. When using do not eat, drink or smoke. Use only in an area containing flame proof equipment. Take precautionary measures against static discharges. For personal protection see section "Exposure controls/personal protection".

Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from combustible material. Keep in an area equipped with sprinklers. Keep away from food, drink and animal feedingstuffs. No smoking.

Specific end use(s)
Registered Crop Protection products: For proper and safe use of this product, please refer to the approval conditions laid down on the product label.

Transport information

Land transport (ADR/RID)

UN number:
UN 1993
Shippingopen allclose all
Class:
3
Packaging group:
III
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
-
Shippingopen allclose all
Class:
-
Classification code:
-
Packaging group:
-
Labels:
-
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 1993
Proper shipping name and description:
2-Isopropylsulfanyl-3-(2,2,2-trifluoro-ethoxy)-pyridine
Chemical name:
2-Isopropylsulfanyl-3-(2,2,2-trifluoro-ethoxy)-pyridine
Class:
3
Packaging group:
III
EmS code:
-
Labels:
3
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 1993
Proper shipping name and description:
2-Isopropylsulfanyl-3-(2,2,2-trifluoro-ethoxy)-pyridine
Chemical name:
2-Isopropylsulfanyl-3-(2,2,2-trifluoro-ethoxy)-pyridine
Class:
3
Packaging group:
III
Labels:
3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at theses sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.


Control parameters
No specific information available for this substance treshold limits.

Threshold limits
-

Other information on limit values
No data available.

DNELs
No data available

PNECS
No data available

Exposure controls
Appropriate engineering controls
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. If airborne mists or vapors are generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice. Protective measures: The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal protective equipment should be certified to appropriate standards.


Individual protection measures

Respiratory protection
ABEK-P3 respirator with fresh air blower is applicable.

Hand protection
No specific data available. Chemical resistant gloves.

Eye/face protection
Safety glasses with side-shields.

Skin protection
Wear suitable protective clothing.

Thermal hazards
No data available.

Environmental exposure controls
Should not be released into the environment.




Stability and reactivity

Reactivity
no information available.

Chemical stability
No information available

Possibility of hazardous reactions
None known. Hazardous polymerisation does not occur.

Conditions to avoid
No information available.

Incompatible materials
No information available.

Hazardous decomposition products
Combustion or thermal decomposition will evolve toxic and irritant vapours.

Disposal considerations

Waste treatment methods
Where possible recycling is preferred to disposal or incineration. It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations.

Waste from residues/unused products
Dispose of as unused product.