Registration Dossier
Registration Dossier
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: - | CAS number: 37486-69-4
Explosiveness
Administrative data
- Endpoint:
- explosiveness
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- November 1 - 2, 2010
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 011
- Report date:
- 2011
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.14 (Explosive properties)
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- EPA OPPTS 830.6316 (Explodability)
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: OECD 113 (1981) Screening test for thermal stability and stability in air
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Details on test material:
- - Name of test material (as cited in study report: MTDID 21721
- Physical state: liquid
- Lot/batch no.: TFEE5-276/12/09-1
- Expiration date of the lot/batch: 31 December 2012
- Storage condition of test material: Room temperature in the dark under nitrogen
Constituent 1
Results and discussion
Small-scale preliminary testsopen allclose all
- Parameter:
- other: More sensitive to shock than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
- Parameter:
- other: More sensitive to friction than m-dinitrobenzene
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
- Parameter:
- other: Explosive under influence of flame
- Remarks:
- migrated information
- Remarks on result:
- not measured/tested
- Parameter:
- other: Explosive (not specified)
- Remarks:
- migrated information
- Remarks on result:
- negative (not further specified)
Any other information on results incl. tables
Test used Differential Scanning Calorimetry in a Mettler-Toledo TA8000 apparatus. TFEE-5 was heated up from ambient to the final temperature (500 °C) at a constant heating rate (3 K/min) under nitrogen. Closed stainless steel crucibles were used as containers for the test item and as empty reference crucible. The measurement showed an exothermic effect in the temperature range of 360 - 450 °C with an energy release of 74 J/g (See Figure). No further thermal effects have been observed up to the maximum temperature of 500 °C. Because the decomposition energy was less than 500 J/g, the test on explosive properties was not necessary per Recommendations on the Transport of Dangerous Goods I Manual of tests and Criteria (ST/SG/AC.10/11/Rev.3)
Applicant's summary and conclusion
- Interpretation of results:
- non explosive
- Remarks:
- Migrated information
- Conclusions:
- TFEE-5 is not explosive
- Executive summary:
Explosiveness of TFEE-5 was addressed using Differential Scanning Calorimetry. TFEE-5 was heated from ambient temperature to 500 °C at a constant rate of 3K/min under nitrogen. An energy release of 74 J/g was noted between 360-450 °C. No other thermal effects were seen. Because the decomposition energy was less than 500 J/g, the test on explosive properties was not necessary per Recommendations on the Transport of Dangerous Goods I Manual of tests and Criteria (ST/SG/AC.10/11/Rev.3). TFEE-5 is not explosive.
This test was performed according to internationally-accepted guidelines and under GLP criteria. It is reliable without restrictions.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
