Registration Dossier
Registration Dossier
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EC number: 213-156-1 | CAS number: 927-62-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General advice
Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself.
Inhalation
Keep at rest. Aerate with fresh air. Call a physician immediately. Symptoms of poisoning may develop many hours after exposure.
Eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.
Skin
Wash off with 3% acetic acid followed by large amounts of plain water for at least 5 min as a final step. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.
Ingestion
Call a physician immediately. Do not induce vomiting without medical advice.
Main symptoms
shortness of breath, convulsions, cough, hypertensive effect.
Special hazard
Stomach perforation, Lung oedema, Pneumonia.
Notes to physician
Treat as an alkaline substance (similar to ammonia). If ingested, irrigate the stomach. Treat skin and mucous membranes with antihistamine and corticoids. In case of lung irritation, first treatment with cortisone spray. Symptoms may be delayed. Later control for pneumonia and lung oedema.
Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself.
Inhalation
Keep at rest. Aerate with fresh air. Call a physician immediately. Symptoms of poisoning may develop many hours after exposure.
Eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.
Skin
Wash off with 3% acetic acid followed by large amounts of plain water for at least 5 min as a final step. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.
Ingestion
Call a physician immediately. Do not induce vomiting without medical advice.
Main symptoms
shortness of breath, convulsions, cough, hypertensive effect.
Special hazard
Stomach perforation, Lung oedema, Pneumonia.
Notes to physician
Treat as an alkaline substance (similar to ammonia). If ingested, irrigate the stomach. Treat skin and mucous membranes with antihistamine and corticoids. In case of lung irritation, first treatment with cortisone spray. Symptoms may be delayed. Later control for pneumonia and lung oedema.
Fire-fighting measures
Suitable extinguishing media
alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water spray
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases
Under conditions giving incomplete combustion, hazardous gases produced may consist of:
carbon monoxide (CO)
carbon dioxide (CO2)
nitrogen oxides (NOx)
Combustion gases of organic materials must in principle be graded as inhalation poisons
Vapour is heavier than air and can travel considerable distance to a source of ignition and flashback
Special protective equipment for fire-fighters
Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full fire-fighting turn out gear.
Precautions for fire-fighting
Cool containers / tanks with water spray. Keep people away from and upwind of fire. Dike and collect water used to fight fire. Water run-off and vapor cloud may be corrosive.
alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water spray
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases
Under conditions giving incomplete combustion, hazardous gases produced may consist of:
carbon monoxide (CO)
carbon dioxide (CO2)
nitrogen oxides (NOx)
Combustion gases of organic materials must in principle be graded as inhalation poisons
Vapour is heavier than air and can travel considerable distance to a source of ignition and flashback
Special protective equipment for fire-fighters
Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full fire-fighting turn out gear.
Precautions for fire-fighting
Cool containers / tanks with water spray. Keep people away from and upwind of fire. Dike and collect water used to fight fire. Water run-off and vapor cloud may be corrosive.
Accidental release measures
Personal precautions
Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep people away from and upwind of spill/leak. Ensure adequate ventilation, especially in confined areas. Keep away from heat and sources of ignition.
For emergency responders: Personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment (biological treatment plant).
Methods for containment
Stop the flow of material, if possible without risk. Dike spilled material, where this is possible.
Methods for cleaning up
Soak up with inert absorbent material. DO NOT use combustible materials such as sawdust. Keep in suitable, closed containers for disposal. If liquid has been spilt in large quantities clean up promptly by scoop or vacuum. Dispose of in accordance with local regulations. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).
Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep people away from and upwind of spill/leak. Ensure adequate ventilation, especially in confined areas. Keep away from heat and sources of ignition.
For emergency responders: Personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment (biological treatment plant).
Methods for containment
Stop the flow of material, if possible without risk. Dike spilled material, where this is possible.
Methods for cleaning up
Soak up with inert absorbent material. DO NOT use combustible materials such as sawdust. Keep in suitable, closed containers for disposal. If liquid has been spilt in large quantities clean up promptly by scoop or vacuum. Dispose of in accordance with local regulations. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).
Handling and storage
Handling
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Provide sufficient air exchange and/or exhaust in work rooms. Refill and handle product only in closed system.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be available. Ground and bond containers when transferring material. Vapour is heavier than air and can travel considerable distance to a source of ignition and flashback.
Advice on the protection of the environment
See Section 8: Environmental exposure controls.
Storage
Technical measures/Storage conditions
Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care. Handle under nitrogen, protect from moisture. Keep at temperatures between -1 and 38 °C (30 and 100 °F).
Advice on common storage
Incompatible products:
strong acids
oxidizing agents
Temperature class
T4
Identified uses
Transported isolated intermediate (1907/2006)
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Provide sufficient air exchange and/or exhaust in work rooms. Refill and handle product only in closed system.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be available. Ground and bond containers when transferring material. Vapour is heavier than air and can travel considerable distance to a source of ignition and flashback.
Advice on the protection of the environment
See Section 8: Environmental exposure controls.
Storage
Technical measures/Storage conditions
Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care. Handle under nitrogen, protect from moisture. Keep at temperatures between -1 and 38 °C (30 and 100 °F).
Advice on common storage
Incompatible products:
strong acids
oxidizing agents
Temperature class
T4
Identified uses
Transported isolated intermediate (1907/2006)
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 2734
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, flammable, n.o.s.
- Chemical name:
- (N,N-Dimethyl-n-butylamine)
- Language:
- English
- Labels:
- 8
3
Special provisions / remarks
- Special provisions:
- 274
- Remarks:
- Hazard number 883
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2737
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, flammable, n.o.s.
- Chemical name:
- (N,N-Dimethyl-n-butylamine)
- Language:
- English
- Labels:
- 8
3
Special provisions / remarks
- Remarks:
- ADN Tanker forbidden
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2734
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, flammable, n.o.s.
- Chemical name:
- (N,N-Dimethyl-n-butylamine)
- Labels:
- 8
3
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 2734
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, flammable, n.o.s.
- Chemical name:
- (N,N-Dimethyl-n-butylamine)
- Labels:
- 8
3
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Occupational exposure controls
Engineering measures
General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local ventilation is usually preferred. Explosion-proof equipment (for example fans, switches, and grounded ducts) should be used in mechanical ventilation systems.
Personal protective equipment
General industrial hygiene practice
Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before breaks and immediately after handling the product.
Respiratory protection
Respirator with A filter. Full mask with above mentioned filter according to producers using requirements or self-contained breathing apparatus. Equipment should conform to EN 136 or EN 140 and EN 143.
Hand protection
Wear protective gloves. Recommendations are listed below. Other protective material may be used, depending on the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction with this chemical, material selection should be based on protection for all chemicals present.
Suitable material nitrile rubber
Evaluation according to EN 374: level 6
Glove thickness approx 0,55 mm
Break through time > 480 min
Suitable material polyvinylchloride
Evaluation Information derived from practical experience
Glove thickness approx 0,8 mm
Eye protection
Tightly fitting safety goggles. In addition to goggles, wear a face shield if there is a reasonable chance for splash to the face.
Equipment should conform to EN 166
Skin and body protection
Impervious clothing. Wear face-shield and protective suit for abnormal processing problems.
Environmental exposure controls
Use product only in closed system. If leakage can not be prevented, the substance needs to be suck off at the emersion point, if possible without danger. Observe the exposure limits, clean exhaust air if needed. If recycling is not practicable, dispose of in compliance with local regulations. Inform the responsible authorities in case of leakage into the atmosphere, or of entry into waterways, soil or drains.
Engineering measures
General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local ventilation is usually preferred. Explosion-proof equipment (for example fans, switches, and grounded ducts) should be used in mechanical ventilation systems.
Personal protective equipment
General industrial hygiene practice
Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before breaks and immediately after handling the product.
Respiratory protection
Respirator with A filter. Full mask with above mentioned filter according to producers using requirements or self-contained breathing apparatus. Equipment should conform to EN 136 or EN 140 and EN 143.
Hand protection
Wear protective gloves. Recommendations are listed below. Other protective material may be used, depending on the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction with this chemical, material selection should be based on protection for all chemicals present.
Suitable material nitrile rubber
Evaluation according to EN 374: level 6
Glove thickness approx 0,55 mm
Break through time > 480 min
Suitable material polyvinylchloride
Evaluation Information derived from practical experience
Glove thickness approx 0,8 mm
Eye protection
Tightly fitting safety goggles. In addition to goggles, wear a face shield if there is a reasonable chance for splash to the face.
Equipment should conform to EN 166
Skin and body protection
Impervious clothing. Wear face-shield and protective suit for abnormal processing problems.
Environmental exposure controls
Use product only in closed system. If leakage can not be prevented, the substance needs to be suck off at the emersion point, if possible without danger. Observe the exposure limits, clean exhaust air if needed. If recycling is not practicable, dispose of in compliance with local regulations. Inform the responsible authorities in case of leakage into the atmosphere, or of entry into waterways, soil or drains.
Stability and reactivity
Stability
Stable under recommended storage conditions.
Conditions to avoid
Avoid contact with heat, sparks, open flame and static discharge. Avoid any source of ignition.
Materials to avoid
strong acids, oxidizing agents.
Hazardous decomposition products
No decomposition if stored and applied as directed. If heated to thermal decomposition the following decomposition products may occur depending on the conditions. carbon monoxide (CO). carbon dioxide (CO2). nitrogen oxides (NOx). cyanides. nitric acid. nitriles.
Stable under recommended storage conditions.
Conditions to avoid
Avoid contact with heat, sparks, open flame and static discharge. Avoid any source of ignition.
Materials to avoid
strong acids, oxidizing agents.
Hazardous decomposition products
No decomposition if stored and applied as directed. If heated to thermal decomposition the following decomposition products may occur depending on the conditions. carbon monoxide (CO). carbon dioxide (CO2). nitrogen oxides (NOx). cyanides. nitric acid. nitriles.
Disposal considerations
Product Information
Disposal required in compliance with all waste management related state and local regulations. The choice of the appropriate method of disposal depends on the product composition by the time of disposal as well as the local statutes and possibilities for disposal.
Hazardous waste according to European Waste Catalogue (EWC)
Uncleaned empty packaging
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.
Disposal required in compliance with all waste management related state and local regulations. The choice of the appropriate method of disposal depends on the product composition by the time of disposal as well as the local statutes and possibilities for disposal.
Hazardous waste according to European Waste Catalogue (EWC)
Uncleaned empty packaging
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
