Registration Dossier

Administrative data

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2014
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: No guideline was reported, but the study was well documented and similar to OECD Guideline 103. Therefore this study is classified as reliable with restrictions.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2014
Report Date:
2014

Materials and methods

Test guideline
Qualifier:
equivalent or similar to
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Deviations:
not specified
GLP compliance:
not specified
Type of method:
dynamic method

Test material

Reference
Name:
Unnamed
Type:
Constituent
Test material form:
not specified
Details on test material:
- Name of test material (as cited in study report): lodoctafluorhexen
- Other: Test substance is oxygen, light, and temperature sensitive

Results and discussion

Boiling point
Boiling pt.:
135.4 °C
Atm. press.:
101.325 kPa

Any other information on results incl. tables

Instruments used:

All-glass ebulliometer with Cotrell tube and enclosed electric heating element. The apparatus was wrapped in aluminum foil to protect the test substance against light.

MKS Baratron 628 D Capacitance Manometer

Burster Kelvimat 4323 Pt100 Precision Thermometer

 

The substance was introduced into a boiling cell. Degassing of the test substance was not considered necessary. The lowest test pressure was selected and the heating power was increased until the test substance reached a study reflux in the Cotrell tube and measuring cell boiling temperature and pressure were recorded. Then the pressure was set for a higher absolute pressure and the test substance was heated further until a new reflux point was established. The pressure level was raised in increments until 10 boiling point and pressure pairs were recorded. Before the test, results at zero point and at atmospheric pressure were checked a versus laboratory manometer.

Applicant's summary and conclusion

Conclusions:
The boiling point of IOFH is 135.4 °C at 101.325 kPa.
Executive summary:

The boiling point of IOFH was extrapolated from the measured data for the compound using the dynamic method. Vapor pressure and temperature were recorded at a variety of equilibrium points up to a temperature of 128 °C and fit to the Antoine equation. The resulting equation wasPvap [Pa] = exp(20.8255 – 3178.69 / (-66.7278 + T [K]). No method was reported, but the dynamic method is approved for this endpoint per OECD TG 103. No information about GLP compliance was available. Therefore, the study is classified as acceptable with restrictions.