Registration Dossier

Administrative data

First-aid measures

General tip: Instantly remove any clothing soiled by the product.
After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. Seek immediate medical advice.
After skin contact: Instantly wash with water and soap and rinse thoroughly. Seek immediate medical advice.
After swallowing: Seek immediate medical advice.
After eye contact: Rinse opened eye for several minutes under running water. Then consult doctor.
Indication of immediate medical attention and special treatment needed: No information available

Fire-fighting measures

Suitable extinguishing agents: CO2, extinguishing powder, water spray jet, extinguishing foam
Don’t use: ---
Special hazards: Combustible. Vapours heavier than air. Formation of explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Special safety equipment: Do not stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.
The following may develop in event of fire: Nitrogen oxides, Carbon monoxide, Carbon dioxide, Silicon dioxide.
Further Information: Contain escaping vapours with water. Prevent fire-fighting water from entering surface water or groundwater.

Accidental release measures

Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation.
Keep away from ignition sources.
Measures for environmental protection: Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting: Absorb with liquid binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose of contaminated material as waste according to disposal considerations.
Ensure adequate ventilation.
Keep away from ignition sources.
Additional information: See information on safe handling , information on personal protection equipment and information on disposal.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Handling:
Information for safe handling:
Handle under dry protective gas.
Keep containers tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires: Keep ignition sources away – Do not smoke. Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Storage:
Information about storage in one common storage facility: Store away from oxidizing agents. Protect from heat. Store away from water.
Further information about storage conditions: Store under dry inert gas.
This product is moisture sensitive.
Keep container tightly sealed.
Store in a locked cabinet or with access restricted to technical experts or their assistants.

Transport information

Land transport (ADR/RID)

UN number:
2920
Proper shipping name and description:
ÄTZENDER FLÜSSIGER STOFF, ENTZÜNDBAR N.A.G., N,O-BIS(TRIMETHYLSILYL)ACETAMIDE
Language:
German
Class:
8 (CF1)
Packaging group:
II
Labels:
8+3
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2920
Proper shipping name and description:
CORROSIVE LIQUID, FLAMMABLE, N.O.S. (N,OBIS(TRIMETHYLSILYL)ACETAMIDE)
Class:
8
Packaging group:
II
EmS code:
F-E, S-C
Labels:
8+3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2920
Proper shipping name and description:
corrosive liquid, flammable, N.O.S. (N,OBis(trimethylsilyl)acetamide)
Class:
8(3)
Packaging group:
II
Labels:
8+3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Additional information about design of technical systems: Not required.
Components with critical values that require monitoring at the workplace: Not required.
Additional information: No data
Personal protective equipment: Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier.
Respiratory protection: Required when vapours/aerosols are generated
Eye protection: Safety glasses.
Body protection: Protective work clothing
Hand protection:
In full contact: Glove material: butyl; Layer thickness: 0,7 mm; Breakthrough time: > 480 min
In splash contact: Glove material: nitril; Layer thickness: 0,4 mm; Breakthrough time: > 30 min
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN 374.
Industrial hygiene: Immediately change contaminated clothing. Wash hands and face after working.
Apply skin-protective barrier cream.

Stability and reactivity

Thermal decomposition/conditions to be avoided: No decomposition if used and stored according to specifications.
Chemical stability: sensitive to moisture
Dangerous reactions: Contact with water releases flammable gases. Reacts with acids. Reacts with alcohols.
Conditions to avoid: warming
Materials to be avoided: Water/moisture; Oxidizing agents, Avoid strong heating
Dangerous products of decomposition: Carbon monoxide and carbon dioxide

Disposal considerations

Product:
Recommendation:
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Consult state, local or national regulations for proper disposal.
Packaging: Disposal in compliance with official regulation. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminate packaging may treated like household waste or recycled.