Registration Dossier

Administrative data

First-aid measures

Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin.
Drench the affected skin with running water for 10 minutes or longer if substance is still
on skin.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water
to drink immediately. If unconscious, check for breathing and apply artificial respiration if
necessary. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If
conscious, ensure the casualty sits or lies down. If unconscious, check for breathing
and apply artificial respiration if necessary. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach
pain may occur. There may be vomiting. Convulsions may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Absorption
through the lungs can occur causing symptoms similar to those of ingestion. [cont...]

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Fire-fighting measures

Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Dry chemical
powder. Water spray. Alcohol or polymer foam.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Harmful. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In
combustion, emits toxic fumes of phosphorus oxides. In combustion emits toxic fumes
of hydrogen chloride / phosgene.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
with skin and eyes.

Accidental release measures

Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: If outside do not approach from downwind. Mark out the contaminated area with signs
and prevent access to unauthorised personnel. Do not attempt to take action without
suitable protective clothing - see section 8 of SDS. Do not create dust.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific
substance. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

Handling and storage

Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is exhaust ventilation of the area.
Avoid the formation or spread of dust in the air.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. Avoid contact with water
or humidity. Keep away from direct sunlight.
Suitable packaging: Glass. Polyethylene.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methoxymethyl-triphenyl-phosphonium-chloride)
Chemical name:
Methoxymethyl-triphenyl-phosphonium-chloride
Class:
9
Packaging group:
III
EmS code:
F-A; S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3977
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Methoxymethyl-triphenyl-phosphonium-chloride)
Chemical name:
Methoxymethyl-triphenyl-phosphonium-chloride
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters
8.2. Exposure controls
Engineering measures: Ensure there is exhaust ventilation of the area. Ensure all engineering measures
mentioned in section 7 of SDS are in place.
Respiratory protection: Respiratory protective device with particle filter. Self-contained breathing apparatus must
be available in case of emergency.
Hand protection: Protective gloves. Nitrile gloves.
Eye protection: Safety glasses with side-shields. Face-shield. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.
Environmental: Prevent from entering in public sewers or the immediate environment.

Stability and reactivity

Section 10: Stability and reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
10.4. Conditions to avoid
Conditions to avoid: Heat. Direct sunlight. Humidity.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In combustion,
emits toxic fumes of phosphorus oxides. In combustion emits toxic fumes of hydrogen
bromide.

Disposal considerations

Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
company.
Disposal of packaging: Burn in a chemical incinerator equipped with afterburners and scrubbers.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.