Registration Dossier

Administrative data

First-aid measures

- After inhalation:
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.

- After skin contact:
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.

- After eye contact:
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.

- After swallowing: Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

Fire-fighting measures

- Suitable extinguishing agents:
Water spray, Carbon dioxide (CO2), Foam, Sand

- Special hazards caused by the material, its products of combustion or resulting gases:
Hydrogen chloride (HCl), Carbon monoxide (CO)

- Protective equipment:
In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.

- Additional information:
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

- Person-related safety precautions:
Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Remove all sources of ignition.

- Measures for environmental protection:
Do not allow to get into surface water, drains and ground water.

- Measures for cleaning/collecting:
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust).
Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal. Decontaminate tools and equipment following cleanup.

Handling and storage

Manufacture and use takes place under strictly controlled conditions. The substance is rigorously contained (production, use), appropriate risk management measures are applied and a management system is in place. An authorisation scheme covers the process and a procedure ensures that only trained and authorised persons handle the substance. Process procedures for containment during cleaning and maintenance have been accounted for in plant and engineering design as appropriate for the site. Procedures to ensure containment have been applied for all stages of production and processing. Occupational procedures have been assessed and are documented.


- Advice on safe handling:
Use only in area provided with appropriate exhaust ventilation.

- Advice on protection against fire and explosion:
Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.

- Hygiene measures:
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower.
Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).

Transport information

Land transport (ADR/RID)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
(1-CHLOROCYCLOPROPYL-METHYLKETONE)
Chemical name:
1-(1chlorocyclopropyl)ethanone
Language:
English
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
3
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
(1-CHLOROCYCLOPROPYL-METHYLKETONE)
Chemical name:
1-(1chlorocyclopropyl)ethanone
Class:
3
Packaging group:
III
EmS code:
F-E, S-E
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
(1-CHLOROCYCLOPROPYL-METHYLKETONE )
Chemical name:
1-(1chlorocyclopropyl)ethanone
Class:
3
Packaging group:
III
Labels:
3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of theregistrant’s intermediate.


- Advice on safe handling:
Use only in area provided with appropriate exhaust ventilation.

- Advice on protection against fire and explosion:
Keep away from heat and sources of ignition.
Take measures to prevent the build up of electrostatic charge.

- Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands immediately after work, if necessary take a shower.
Remove soiled clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).


Personal precautions while handling the product:

- respiratory protection:
Wear respirator with an organic vapours and gas filter mask (protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

- eye protection:
Wear goggles conforming to EN166 (Field of Use 5 or equivalent).

- hand:
Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.

- skin and body protection:
Wear standard coverall and type 3 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently. If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

Stability and reactivity

- Thermal decomposition: from 155 °C, Heating rate:5 K/min; exothermic decomposition.

- Chemical stability: Stable under recommended storage conditions.

- Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use.

- Conditions to avoid: Extremes of temperature and direct sunlight.

- Incompatible materials: Store only in the original container.

- Hazardous decomposition products: No decomposition products expected under normal conditions of use.

Disposal considerations

During the whole life cycle of the substance all necessary measures in accordance to art. 18(4) of (EC) 1907/2006 are undertaken. The substance is handled under strictly controlled conditions.

In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a incineration plant.