Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

SKIN CONTACT: Remove contaminated clothing immediately. Wash off with plenty of water for 30 minutes. Get medical attention. The person who is giving first aid, should wear personal protective equipment.
EYE CONTACT: Rinse thoroughly with plenty of water, also under the eyelids, for 30 minutes. Get immediate medical attention. The person who is giving first aid, should wear personal protective equipment.
INHALATION: Breathe fresh air and rest. Oxygen and artificial respiration if needed. Get immediate medical attention.
INGESTION: If victim is conscious, immediately rinse mouth with water and give large quantities of water to drink. DO NOT induce vomiting. Get immediate medical attention.

Fire-fighting measures

SUITABLE EXTINGUISHING MEDIA: Water, dry chemical.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: In the event of fire, wear self-contained breathing apparatus and full protective gear.

Accidental release measures

PERSONAL PRECAUTIONS: Avoid contact with eyes, skin and clothing. Do not breathe vapours. Wear personal protective equipment. Isolate the area. Prevent further leakage or spillage if safe to do so. Apply water spray or mist to knock down vapors.
ENVIRONMENTAL PRECAUTIONS: Avoid release to the environment. Do not flush into surface waters or sanitary sewer system. If the product contaminates waterways or drains inform respective authorities.
METHODS FOR CLEANING UP: Absorb with non-combustible materials such as sand or earth and collect in a suitable container to be disposed of in accordance with local regulations DO NOT use acids to neutralize.

Handling and storage

HANDLING: Advice on safe handling: Avoid contact with eyes, skin and clothes. Do not breathe vapours. Do not heat up. Keep away from acids. Use only in well-ventilated areas. The solution should be kept strongly alkaline (pH > 10) in order to avoid release of gaseous hydrogen sulfide.
Advice on protection against fire and explosion: The product itself is not flammable. When heated, may produce highly flammable and toxic hydrogen sulfide gas.
STORAGE:
- Keep in a cool and well-ventilated place.
- Keep only in the original container. Keep the container tightly closed.
- Keep away from acids and heat sources.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2949
Shipping information
Proper shipping name and description:
SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization
Chemical name:
Reaction mass of sodium hydrogensulfide and sodium carbonate.
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

EXPOSURE CONTROLS
1) Respiratory protection
- In case of vapours/fog/fumes; gas mask type B2.
2) Hand protection
- Protective gloves
- Suitable material : PVC, Neoprene
3) Eye protection
- Chemical resistant goggles or face shield must be worn.
4) Skin and body protection
- Protective suit and boots.
5) Hygiene measures
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls:
- Avoid release in the environment.

Stability and reactivity

HAZARDOUS REACTIONS: Contact with acids liberates flammable and toxic gas (H2S). May be corrosive to metals.
CONDITIONS TO AVOID: Heat, moisture.
HAZARDOUS DECOMPOSITION PRODUCTS: hydrogen sulfide.

Disposal considerations

WASTE FROM RESIDUES / UNUSED PRODUCTS
- Hazardous waste
-Dispose of in accordance with local and national regulations and with the European Directives on waste and hazardous waste.