3-chloroaniline

Guidance on Safe Use

First-aid measures

Inhalation: Get medical attention immediately. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Ingestion: Get medical attention immediately. Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If

material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact: Get medical attention immediately. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact: Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.

Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.

Unsuitable extinguishing media: None known.

Special hazards arising from the substance or mixture

Hazards from the substance or mixture: In a fire or if heated, a pressure increase will occur and the container may burst.

Hazardous combustion products: Decomposition products may include the following materials: carbon oxides, nitrogen oxides, halogenated compounds.

Advice for firefighters

Special precautions for firefighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is very toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment (see Section: Exposure controls/personal protection).

Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Methods and materials for containment and cleaning up:

Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material

and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas.

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section: Disposal considerations). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see SDS section 1 for emergency contact information and section: Disposal consioderations for waste disposal.

Reference to other sections: See SDS section 1 for emergency contact information. See Section: Exposure controls/personal protection for information on appropriate personal protective

equipment. See Section. Disposal considerations for additional waste treatment information.

Handling and storage

Precautions for safe handling: Put on appropriate personal protective equipment (see Section: Exposure controls/personal protection). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.

Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section: stability and reactivity) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Specific end use(s) Recommendations: Not available

Industrial sector specific solutions: Not available

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

Control parameters Exposure limit values: Not available.

Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective

equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Exposure controls

Risk management measures

Occupational exposure controls - Technical measures: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Personal protection meqasures:

Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Full mask with type ABEK filter if product forms vapours / Wear breathing apparatus with separate air supply (compressed air respirator, tube apparatus) at higher concentrations.

Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical

products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations Recommended: (< 1 hour) Baypren -/Viton® - or Rubber gloves.

Eye protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid

exposure to liquid splashes, mists, gases or dusts. Recommended: Tightly fitting safety goggles.

Skin protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should

be approved by a specialist before handling this product. Recommended: Wear protective clothing.

Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated

clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls:

Technical measures: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of

environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product orits ingredients.

Chemical stability: The product is stable.

Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Condidtions to avoid: Air and light-sensitive. Incompatible materials : acids , acid chloride, acid anhydride , strong oxidizing agents . Hazardous decomposition products : hydrogen chloride , carbon monoxide , Carbon dioxide, nitrogen .

Incompatible materials: No specific data.

Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Disposal considerations

Product:

methods of disposal: Examine possibilities for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed, labelled,

and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned, consult the supplier. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste List (EWL).

Hazarous waste: The classification of the product may meet the criteria for a hazardous waste.

Packaging:

Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or

landfill should only be considered when recycling is not feasible.

Special precautions: This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.