Registration Dossier
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EC number: 201-956-3 | CAS number: 89-98-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
After inhalation:
Remove the victim into fresh air
Respiratory problems: consult a doctor/medical service.
Skin contact:
Wash immediately with lots of water (15 minutes)/shower
Remove clothing while washing
Do not apply (chemical) neutralizing agents
Do not remove clothing if it sticks to the skin
Cover wounds with sterile bandage
Consult a doctor/medical service
If burned surface > 10%: take victim to hospital
Eye contact:
Rinse immediately with plenty of water for 15 minutes
Take victim to an ophthalmologist
Do not apply neutralizing agents
After ingestion:
Rinse mouth with water
Immediately after ingestion: give lots of water to drink
Do not induce vomiting
Immediately consult a doctor/medical service
Remove the victim into fresh air
Respiratory problems: consult a doctor/medical service.
Skin contact:
Wash immediately with lots of water (15 minutes)/shower
Remove clothing while washing
Do not apply (chemical) neutralizing agents
Do not remove clothing if it sticks to the skin
Cover wounds with sterile bandage
Consult a doctor/medical service
If burned surface > 10%: take victim to hospital
Eye contact:
Rinse immediately with plenty of water for 15 minutes
Take victim to an ophthalmologist
Do not apply neutralizing agents
After ingestion:
Rinse mouth with water
Immediately after ingestion: give lots of water to drink
Do not induce vomiting
Immediately consult a doctor/medical service
Fire-fighting measures
Suitable extinguishing media:
Water spray
Polyvalent foam
Alcohol-resistant foam
Polymer foam
BC powder
Carbon dioxide
Unsuitable extinguishing media:
No unsuitable extinguishing media known
Special exposure hazards:
Temperature above flashpoint: higher fire/explosion hazard
On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, carbon monoxide - carbon dioxide)
Instructions:
Cool tanks/drums with water spray/remove them into safety
Dilute toxic gases with water spray
Take account of toxic fire-fighting water
Use water moderately and if possible collect or contain it
Special protective equipment for fire-fighters:
Gloves
Face-shield
Corrosionproof suit
Large spills/in enclosed spaces: compressed air apparatus
Large spills/in enclosed spaces: gas-tight suit
Heat/fire exposure: compressed air/oxygen apparatus
Water spray
Polyvalent foam
Alcohol-resistant foam
Polymer foam
BC powder
Carbon dioxide
Unsuitable extinguishing media:
No unsuitable extinguishing media known
Special exposure hazards:
Temperature above flashpoint: higher fire/explosion hazard
On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, carbon monoxide - carbon dioxide)
Instructions:
Cool tanks/drums with water spray/remove them into safety
Dilute toxic gases with water spray
Take account of toxic fire-fighting water
Use water moderately and if possible collect or contain it
Special protective equipment for fire-fighters:
Gloves
Face-shield
Corrosionproof suit
Large spills/in enclosed spaces: compressed air apparatus
Large spills/in enclosed spaces: gas-tight suit
Heat/fire exposure: compressed air/oxygen apparatus
Accidental release measures
Occupational exposure controls:
Carry operations in the open/under local exhaust/ventilation or with respiratory protection Personal protective equipment:
a) Respiratory protection:
High gas/vapour concentration: gas mask with filter type A
b) Hand protection:
Gloves
- neoprene
- rubber
- viton
c) Eye protection:
Face shield
d) Skin protection:
Corrosionproof clothing
Environmental precautions:
Contain released substance, pump into suitable containers
Plug the leak, cut off the supply
Dam up the liquid spill
Take account of toxic/corrosive precipitation water
Prevent soil and water pollution
Prevent spreading in sewers
Methods for cleaning up:
Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite or kieselguhr
Scoop absorbed substance into closing containers
Carefully collect the spill/leftovers
Damaged/cooled tanks must be emptied
Clean contaminated surfaces with an excess of water
Take collected spill to manufacturer/competent authority
Wash clothing and equipment after handling
Carry operations in the open/under local exhaust/ventilation or with respiratory protection Personal protective equipment:
a) Respiratory protection:
High gas/vapour concentration: gas mask with filter type A
b) Hand protection:
Gloves
- neoprene
- rubber
- viton
c) Eye protection:
Face shield
d) Skin protection:
Corrosionproof clothing
Environmental precautions:
Contain released substance, pump into suitable containers
Plug the leak, cut off the supply
Dam up the liquid spill
Take account of toxic/corrosive precipitation water
Prevent soil and water pollution
Prevent spreading in sewers
Methods for cleaning up:
Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite or kieselguhr
Scoop absorbed substance into closing containers
Carefully collect the spill/leftovers
Damaged/cooled tanks must be emptied
Clean contaminated surfaces with an excess of water
Take collected spill to manufacturer/competent authority
Wash clothing and equipment after handling
Handling and storage
Handling:
Use earthed equipment
Observe strict hygiene
Keep away from naked flames/heat
Keep container tightly closed
At temp>flashpoint: use spark-/explosionproof appliances
Finely divided: spark- and explosionproof appliances
Finely divided: keep away from ignition sources/sparks
Do not discharge the waste into the drain
Storage:
Safe storage requirements:
Store in a dry area
Store in a dark area
Ventilation at floor level
Keep locked up
Provide for a tub to collect spills
May be stored under nitrogen
Meet the legal requirements
Storage temperature: 20 - 40 °C
Keep away from:
oxidizing agents
reducing agents
(strong) bases
water/moisture
Use earthed equipment
Observe strict hygiene
Keep away from naked flames/heat
Keep container tightly closed
At temp>flashpoint: use spark-/explosionproof appliances
Finely divided: spark- and explosionproof appliances
Finely divided: keep away from ignition sources/sparks
Do not discharge the waste into the drain
Storage:
Safe storage requirements:
Store in a dry area
Store in a dark area
Ventilation at floor level
Keep locked up
Provide for a tub to collect spills
May be stored under nitrogen
Meet the legal requirements
Storage temperature: 20 - 40 °C
Keep away from:
oxidizing agents
reducing agents
(strong) bases
water/moisture
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3265
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Environmental exposure controls:
Avoid discharge into the environment.
According to local regulations, Federal and official regulations.
Environmental exposure controls:
Avoid discharge into the environment.
According to local regulations, Federal and official regulations.
Stability and reactivity
Conditions to avoid:
Possible fire hazard
heat sources
Stability
Unstable on exposure to moisture
Unstable on exposure to air
Unstable on exposure to light
Reactions
Oxidizes slowly on exposure to air
Reacts exothermically with many compounds e.g.: with (some) bases, with (strong) oxidizers and with (strong) reducers
Materials to avoid:
oxidizing agents
reducing agents
(strong) bases
water/moisture
Hazardous decomposition products:
On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, carbon monoxide - carbon dioxide)
Possible fire hazard
heat sources
Stability
Unstable on exposure to moisture
Unstable on exposure to air
Unstable on exposure to light
Reactions
Oxidizes slowly on exposure to air
Reacts exothermically with many compounds e.g.: with (some) bases, with (strong) oxidizers and with (strong) reducers
Materials to avoid:
oxidizing agents
reducing agents
(strong) bases
water/moisture
Hazardous decomposition products:
On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, carbon monoxide - carbon dioxide)
Disposal considerations
Provisions relating to waste:
Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001) 07 04 03* : organic halogenated solvents, washing liquids and mother liquors
Depending on branch of industry and production process, also other EURAL codes may be applicable
Hazardous waste (91/689/EEC)
Disposal methods:
Recycle/reuse
Remove to an incinerator for chlorinated waste materials with energy recovery
Remove waste in accordance with local and/or national regulations
Do not discharge into drains or the environment
Packaging/Container:
Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001):
15 01 10* : packaging containing residues of or contaminated by dangerous substances
Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001) 07 04 03* : organic halogenated solvents, washing liquids and mother liquors
Depending on branch of industry and production process, also other EURAL codes may be applicable
Hazardous waste (91/689/EEC)
Disposal methods:
Recycle/reuse
Remove to an incinerator for chlorinated waste materials with energy recovery
Remove waste in accordance with local and/or national regulations
Do not discharge into drains or the environment
Packaging/Container:
Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001):
15 01 10* : packaging containing residues of or contaminated by dangerous substances
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