Registration Dossier

Administrative data

First-aid measures

General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may only appear several hours later.
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
In case of eye contact : Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Fire-fighting measures

Suitable extinguishing media : Water, Foam
Specific hazards during firefighting: Formation of corrosive gases by combustion.
Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus.
Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Consider dust explosion hazard.

Accidental release measures

Evacuate personnel to safe areas. Use personal protective equipment.
Ensure adequate ventilation.
Avoid dust formation.
Avoid breathing dust.

Environmental precautions:
Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust.
Keep in suitable, closed containers for disposal.
Avoid formation of dust and aerosols.

Handling and storage

Advice on safe handling : Avoid formation of respirable particles.
Avoid exceeding of the given occupational exposure limits.
Avoid contact with skin and eyes.

Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national regulations.
Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion: Avoid dust formation.
Provide appropriate exhaust ventilation at places where dust is formed. Take precautionary measures against static discharges.
Requirements for storage areas and containers: Protect against light. Keep container tightly closed and dry.
Prevent unauthorized access.

Transport information

Land transport (ADR/RID)

UN number:
2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. ((2-ethoxy-1-methyl-2-
oxoethyl)triphenylphosphonium bromide)
Chemical name:
2-ethoxy-1-methyl-2- oxoethyl)triphenylphosphonium bromide
Language:
English
Class:
6.1
Classification code:
T2
Packaging group:
III
Labels:
6, 1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. ((2-ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium bromide)
Chemical name:
2-ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium bromide
Language:
English
Class:
6.1
Classification code:
T2
Packaging group:
III
Labels:
6, 1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. ((2-ethoxy-1-methyl-2-
oxoethyl)triphenylphosphonium bromide)
Chemical name:
2-ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium bromide
Class:
6.1
Packaging group:
III
EmS code:
F-A, S-A
Labels:
6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. ((2-ethoxy-1-methyl-2-
oxoethyl)triphenylphosphonium bromide)
Chemical name:
2-ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium bromide
Class:
T2
Packaging group:
III
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment
Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter.
Hand protection : Glove material: for example nitrile rubber , Consider the hazard characteristics of this product and any
special workplace conditions when selecting the appropriate type of protective gloves.
Eye protection : Safety glasses with side-shields
Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
Do not breathe dust or spray mist. Wash hands before breaks and immediately after handling the product.

Stability and reactivity

Reactivity: No hazards to be specially mentioned
Chemical stability: Stable under recommended storage conditions.
Possibility of hazardous reactions: Dust may form explosive mixture in air
Conditions to avoid: Heat
Incompatible materials: Strong acids and strong bases Strong oxidizing agents
Hazardous decomposition products: No decomposition if used as directed.

Disposal considerations

Product : Do not contaminate ponds, waterways or ditches with chemical or used container.
Do not dispose of waste into sewer.
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging : Dispose of as unused product.
Do not re-use empty containers.