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Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: see 'Remark'
Remarks:
The reliability is rated 2 because the study followed the standard guideline of reference (EU A.16 method), which describes a procedure designed to evaluate this endpoint. The results were reviewed for reliability and assessed as valid. Nevertheless no information was available whether or not the 0study was conducted under GLP condition.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report date:
2011

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
tetrakis{9-[2-(ethoxycarbonyl)phenyl]-3,6-bis(ethylamino)-2,7-dimethylxanthylium} C12-(branched and/or linear)-alkyl-(4-sulfonatophenoxy)benzenesulfonate and oxybis[C12-(branched and/or linear)-alkyl-benzenesulfonate]
EC Number:
700-761-5
Molecular formula:
not applicable
IUPAC Name:
tetrakis{9-[2-(ethoxycarbonyl)phenyl]-3,6-bis(ethylamino)-2,7-dimethylxanthylium} C12-(branched and/or linear)-alkyl-(4-sulfonatophenoxy)benzenesulfonate and oxybis[C12-(branched and/or linear)-alkyl-benzenesulfonate]
Details on test material:
- Name of test material (as cited in study report):Sepisol Fast Red SN
- Substance type: organic salt - UVCB
- Appearance/Physical state: red powder
- Lot/batch No.: 029244

Results and discussion

Any other information on results incl. tables

There is no measurable self-ignition on the Sepisol Fast Red SN up to measurement temperature of 400°C. An endothermic decomposition starts above 200 °C, the sample is always cooler than the oven.

Applicant's summary and conclusion

Conclusions:
In accordance with the DSC measurement, an endothermic decomposition starts above 200°C, the sample is always cooler as the oven. There is no measurable self-ignition of the SEPISOL FAST RED SN up to measurement temperature of 400 °C.
Executive summary:

The purpose of this test was to provide preliminary information on the relative auto-flammability of Sepisol Fast Red SN at elevated temperatures following the EU method A.16.

Approximately 8 mL of the test item is placed in a piece of stainless wire mesh (2x2x2 cm) in an oven at room temperature. Temperature/time curve relating to conditions in the centre of the sample is recorded while the temperature of the oven is increased gradualy to 400 °C.

In accordance with the DSC measurement, an endothermic decomposition starts above 200°C, the sample is always cooler as the oven. There is no measurable self-ignition of the SEPISOL FAST RED SN up to measurement temperature of 400 °C.

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