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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Endpoint:
stability: thermal, sunlight, metals, other
Remarks:
Migrated from section 'Stability: thermal, sunlight, metals'
Type of information:
experimental study
Adequacy of study:
key study
Study period:
22 Jun - 6 Aug 2010
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline study with acceptable restrictions

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: UN H.2
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Octa-1,7-diene
EC Number:
223-054-9
EC Name:
Octa-1,7-diene
Cas Number:
3710-30-3
Molecular formula:
C8H14
IUPAC Name:
octa-1,7-diene

Results and discussion

For thermal stability study

Test substance thermally stable:
yes
Operating temperature
Operating temp.:
> 80 °C

Applicant's summary and conclusion

Conclusions:
result of the thermal stability shows that the substance is stable under testing conditions and does not fulfill the initial criteria for classification of transport class 4.1 "self reactives"
Executive summary:

The sample “1.7-Octadiene” underwent an adiabatic heat storage test (UN H.2 evaluation). The test was conducted as an “overadiabatic” storage test using a 1 litre Dewar vessel (non-hermetically sealed). Using the H.2 evaluation method (according to the UN "Transport of Dangerous Goods") the SADT (Self Accelerating Decomposition Temperature) can be determined for different packaging sizes. No exothermic effects were visible up to a temperature of 118 °C (boiling point). Therefore in a safety conservative consideration (with regard to the relatively far distance to the boiling point) the SADT can be stated >80 °C for arbitrary transport container sizes. From the measurements it can be derived that the sample 1.7-Octadiene does not fulfil the initial criteria for assignment to the transport class 4.1 “self reactives”. Precondition for an assignment would be an SADT of ≤75°C considering a

50 kg packaging size.