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Physical & Chemical properties

Boiling point

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15 December 2011 - 19 March 2012
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Type of method:
differential scanning calorimetry
Boiling pt.:
321 °C
Atm. press.:
1 001 hPa
Decomposition:
yes
Remarks on result:
other: Decomposes on boiling

No endothermic boiling peak is observed. There is an exothermic peak in the 320 to 380 °C region with mean onset 321 °C (see 1) below). This exothermic peak shows pronounced irregularities, indicating an overlap of decomposition and boiling.

To confirm this interpretation, the boiling point was estimated with Syracuse software. The two major components, C16 and C18 alkyl chains, were assumed as the basis for the calculation. The predicted boiling range, 321-346 °C (see 2) below), corresponds to the exothermic peak.

1) Boiling point test results

Measurement

Onset (°C)

Atmospheric pressure (hPa)

#1

320.9

1007

#2

320.7

1007

2) Estimated boiling point (Syracuse)

N,N-dimethyl-C16-alkyl-1-amine: 320.7 °C

N,N-dimethyl-C18-alkyl-1-amine: 345.7 °C

The mean onset (rounded to 321 °C) is selected as giving the best value of the boiling point.

Conclusions:
The boiling point of the test item is 321 °C at 1007 hPa.
Executive summary:

The boiling point of the test substance was determined according to the OECD Guideline 103 using differential scanning calorimetry. At 1007 hPa, the boiling point is 321 °C.

Description of key information

The boiling point of the test item is 321 °C at 1007 hPa.

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
321 °C

Additional information

The boiling point of the test substance was determined according to the OECD Guideline 103 using differential scanning calorimetry. At 1007 hPa, the boiling point is 321 °C.