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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2013
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: well performed study according to acknowledged standards

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013
Report date:
2013

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: VDI 2263 sheet 1
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
4-amino-2,5-dimethoxy-N-methylbenzenesulphonamide
EC Number:
256-435-3
EC Name:
4-amino-2,5-dimethoxy-N-methylbenzenesulphonamide
Cas Number:
49701-24-8
Molecular formula:
C9H14N2O4S
IUPAC Name:
4-amino-2,5-dimethoxy-N-methylbenzene-1-sulfonamide
Details on test material:
purity: 99.7 %

Results and discussion

Auto-ignition temperature (liquids / gases)open allclose all
Auto-ignition temperature:
> 450 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other: no self ignition of the pure substance was observed
Auto-ignition temperature:
ca. 240 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other: 1 : 1 mixture with kieselgur
Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
> 450 °C
Remarks on result:
other: no self ignition of the pure substance was observed
Remarks:
at atm. press. of ca.1.0 atm
Relative self-ignition temperature:
ca. 240 °C
Remarks on result:
other: 1 : 1 mixture with kieselgur
Remarks:
at atm. press. of ca.1.0 atm

Applicant's summary and conclusion

Conclusions:
The substance has not to be clssified as self heating substance acoording to UN-transportation classification and EU-GHS/CLP
Executive summary:

When testing the pure substance for self-ignition according to VDI 2263 sheet 1 in a 8 ml wire basket (Grewer oven) endothermic behaviour was observed starting at 220°C. No exothermic behaviour could be measured up to 450 °C.

A 1:1 mixture of the substance with kieselgur showed also endothermic behavior at about 220 °C and additionally starting at about 240°C exothermic behaviour that resulted in an increase of temperature up to 500 °C