Sodium dibutyldithiocarbamate

GHS

General Information

Implementation:

EU

Type of classification:

self-classification

Remarks:

The substance is solely manufactured and marketed by the registrant as ca. 47% aqueous solution. The provided classification applies to the pure (anhydrous) substance.

Related composition

Related composition:

sodium dibutyldithiocarbamate (solid)

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

hazard class not applicable

Aerosols

Reason for no classification:

hazard class not applicable

Reason for no classification:

hazard class not applicable

Oxidising gases

Reason for no classification:

hazard class not applicable

Gases under pressure

Reason for no classification:

hazard class not applicable

Flammable liquids

Reason for no classification:

hazard class not applicable

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

hazard class not applicable

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

hazard class not applicable

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data lacking

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Hazard category:

Acute Tox. 4

Hazard statement:

H302: Harmful if swallowed.

Acute toxicity - dermal

Hazard category:

Acute Tox. 3

Hazard statement:

H311: Toxic in contact with skin.

Acute toxicity - inhalation

Reason for no classification:

data conclusive but not sufficient for classification

Skin corrosion / irritation

Hazard category:

Skin Corr. 1C

Hazard statement:

H314: Causes severe skin burns and eye damage.

Serious eye damage / eye irritation

Hazard category:

Eye Damage 1

Hazard statement:

H318: Causes serious eye damage.

Respiratory sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Skin sensitisation

Hazard category:

Skin Sens. 1

Hazard statement:

H317: May cause an allergic skin reaction.

Aspiration hazard

Reason for no classification:

data conclusive but not sufficient for classification

Reproductive toxicity

Reason for no classification:

data conclusive but not sufficient for classification

Effects on or via lactation

Reason for no classification:

data conclusive but not sufficient for classification

Germ cell mutagenicity

Reason for no classification:

data conclusive but not sufficient for classification

Carcinogenicity

Reason for no classification:

data conclusive but not sufficient for classification

1. Specific target organ toxicity - single (STOT-SE)

Reason for no classification:

data conclusive but not sufficient for classification

1. Specific target organ toxicity - repeated (STOT-RE)

Hazard category:

STOT Rep. Exp. 2

Hazard statement:

H373: May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

System:

haematopoietic

Affected organs:

bone marrow

spleen

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Hazard category:

Aquatic Acute 1

Hazard statement:

H400: Very toxic to aquatic life.

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 3

Hazard statement:

H412: Harmful to aquatic life with long lasting effects.

Hazardous to the ozone layer

Reason for no classification:

data conclusive but not sufficient for classification

Labelling

Signal word:

Danger

Hazard pictogram

GHS06: skull and crossbones

GHS05: corrosion

GHS08: health hazard

GHS09: environment

Hazard statements

H311: Toxic in contact with skin.

H302: Harmful if swallowed.

H314: Causes severe skin burns and eye damage.

H317: May cause an allergic skin reaction.

H373: May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

H400: Very toxic to aquatic life.

H412: Harmful to aquatic life with long lasting effects.

Precautionary statements

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P260: Do not breathe dust/fume/gas/mist/vapours/spray.

P264: Wash ... thoroughly after handling.

Wash hands thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

P272: Contaminated work clothing should not be allowed out of the workplace.

P273: Avoid release to the environment.

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P352: IF ON SKIN: Wash with plenty of water/…

P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310: Immediately call a POISON CENTER/doctor/…

P363: Wash contaminated clothing before reuse.

P391: Collect spillage.

P405: Store locked up.

P501: Dispose of contents/container to ...