Registration Dossier

Administrative data

First-aid measures

General advice: First aider needs to protect himself.

If inhaled: fresh air. Call in physician.

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.Call a physician immediately.

In case of eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

If swallowed: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately.Do not attempt to neutralise.

Most important symptoms and effects, both acute and delayed:
Symptoms: Irritation and corrosion, Cough, Shortness of breath, Risk of blindness!

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
Fire may cause evolution of:
Hydrogen fluoride

Advice for firefighters
Special protective equipment for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information
Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental precautions
Do not flush into surface water or sanitary sewer system.

Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions.Take up carefully. Dispose of properly. Clean up affected area. Avoid generation of dusts.

Handling and storage

Precautions for safe handling
Advice on safe handling: Provide sufficient air exchange and/or exhaust in work rooms. Do not inhale substance/mixture. Avoid dust formation.
Observe label precautions.

Hygiene measures: Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Store in original container.

Further information on storage conditions: Tightly closed. Dry.

Recommended storage temperature: Recommended storage temperature see product label.

Transport information

Land transport (ADR/RID)

UN number:
UN 1759
Proper shipping name and description:
CORROSIVE SOLID, N.O.S. ( 3,4,5-Trifluorophenol)
Chemical name:
3,4,5-Trifluorophenol
Language:
English
Class:
8
Packaging group:
II
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Marine transport (IMDG)

UN number:
UN 1759
Proper shipping name and description:
CORROSIVE SOLID, N.O.S. ( 3,4,5-Trifluorophenol)
Chemical name:
3,4,5-Trifluorophenol
Class:
8
Packaging group:
II
EmS code:
F-A S-B
Marine pollutant
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Air transport ICAO/IATA

UN number:
UN 1759
Proper shipping name and description:
Corrosive solid, n.o.s.
Chemical name:
3,4,5-Trifluorophenol
Class:
8
Packaging group:
II
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Exposure controls / personal protection

Engineering measures
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.

Personal protective equipment
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled and must meet the specifications of a standard EN/ISO/DIN. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye protection: Tightly fitting safety goggles
Hand protection:
full contact
Glove material: Nitrile rubber
Glove thickness: 0,11 mm
Break through time: 480 min

splash contact
Glove material: Nitrile rubber
Glove thickness: 0,11 mm
Break through time: 480 min

The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example:KCL 741 Dermatril® L(full contact);KCL 741 Dermatril® L(splash contact).
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Protective measures: Protective clothing
Respiratory protection: required when dusts are generated.
Recommended Filter type:: Filter P 3 (acc. to DIN 3181) for solid and liquid particles of toxic and very toxic substances
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Environmental exposure controls
General advice: Do not flush into surface water or sanitary sewer system.

Stability and reactivity

Reactivity
The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Chemical stability
The product is chemically stable under standard ambient conditions (room temperature).

Possibility of hazardous reactions
Violent reactions possible with: Oxidizing agents

Hazardous decomposition products
in the event of fire: See "Fire fighting measures"

Disposal considerations

Waste treatment methods
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.