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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
July - August, 2013
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Remarks:
Guideline study performed non-GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: DIN 51794
Deviations:
no
GLP compliance:
no
Specific details on test material used for the study:
GR-50-1408 is the Givaudan identification code which was employed for ROSYFOLIA during the early, developmental and testing period.
Key result
Auto-ignition temperature:
250 °C
Remarks on result:
other: Auto-ignition temperature determined to be 250 +/- 10°C

Temperature

Injected sample amount

Ignition delay

°C

100 µl

200 µl

300 µl

400 µl

(s)

320

+

 

 

 

2

280

+

 

 

 

20

270

+

 

 

 

40

260

-

+

 

 

54

255

-

+

 

 

111

250

-

-

+

 

121

245

-

-

-

-

-

+  Positive response (flame, blast or deflagration)  - Negative response (nothing or smoke only in a delay of 300 seconds)

Conclusions:
The lowest temperature giving a positive effect was 250°C. The injected volume was 300 microl, the ignition delay was 121 s. At a temperature of 245°C no ignition was observed. Therefore: Auto-ignition temperature of GR-50-1408: 250 +/- 10°C.

Description of key information

The auto-ignition temperature of GR-50-1408 was determined in a SUR BERLIN oven, equipped with a 250ml glass ignition according to the DIN 51794.

The lowest temperature giving a positive effect was 250°C. The injected volume was 300 µl, the ignition delay was 121 s. At a temperature of 245°C no ignition was observed.

Therefore the auto-ignition temperature of GR-50-1408 is 250±10°C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
250 °C

Additional information