Registration Dossier

Administrative data

First-aid measures

Description of first aid measures

General information
Move affected person to fresh air at once. Move affected person to fresh air and keep warm
and at rest in a position comfortable for breathing. Get medical attention.

Inhalation
Move affected person to fresh air at once. For breathing difficulties, oxygen may be
necessary. Get medical attention if any discomfort continues.

Ingestion
Do not induce vomiting. Never give anything by mouth to an unconscious person. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Rinse mouth
thoroughly with water. Get medical attention if any discomfort continues.

Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Get medical attention immediately. Continue to rinse for at least 15 minutes.

Most important symptoms and effects, both acute and delayed

General information
Effects may be delayed. Keep affected person under observation.

Inhalation
Vapours may cause headache, fatigue, dizziness and nausea. Irritating.

Ingestion
May cause discomfort if swallowed. May cause stomach pain or vomiting. Drowsiness,
dizziness, disorientation, vertigo.

Skin contact
May cause serious chemical burns to the skin.

Eye contact
Causes serious eye damage.

Indication of any immediate medical attention and special treatment needed

Notes for the doctor
Effects may be delayed. Keep affected person under observation. Treat symptomatically.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media
Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.

Special hazards arising from the substance or mixture

Specific hazards
Keep container tightly closed. Containers can burst violently or explode when heated, due to excessive pressure build-up. Irritating and/or toxic gases and particulates may be generated by thermal decomposition or combustion.

Advice for firefighters

Protective actions during firefighting
Move containers from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Control run-off water by containing and keeping it out of sewers and watercourses.

Special protective equipment for firefighters

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions
Use approved safety glasses with side shields, or chemical splash goggles and a face shield. Wear protective gloves made of butyl rubber, or viton (fluoro) rubber as advised by supplier/manufacturer with regards to breakthrough-time of the gloves. Wear appropriate clothing to prevent any possibility of skin contact. Respiratory protection complying with an approved standard should be worn if risk assessment indicates inhalation of contaminants is possible.

Environmental precautions

Environmental precautions
Do not discharge into drains or watercourses or onto the ground.

Methods and material for containment and cleaning up

Methods for cleaning up
Provide adequate ventilation. Do not touch or walk into spilled material. Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Smaller quantities of residue may be collected by an absorbent. Collect and place in suitable waste disposal containers and seal securely.

Handling and storage

Precautions for safe handling

Usage precautions
Avoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid inhalation of dust and vapours.

Conditions for safe storage, including any incompatibilities

Storage precautions
Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in the original container.

Storage class
LGK 6.1 C (TRGS 510)

Transport information

Land transport (ADR/RID)

UN number:
2020
Shippingopen allclose all
Class:
6.1
Classification code:
T2
Packaging group:
III
Labels:
6 (Toxic)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2020
Shippingopen allclose all
Class:
6.1
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2020
Proper shipping name and description:
CHLOROPHENOLS, SOLID (4-CHLOROPHENOL)
Class:
6.1
Packaging group:
III
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2020
Proper shipping name and description:
CHLOROPHENOLS, SOLID
Class:
6.1
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters

Ingredient comments
No exposure limits known for ingredient(s).

Exposure controls

Protective equipment

Appropriate engineering controls
Provide adequate general and local exhaust ventilation. All handling should only take place in well-ventilated areas.

Eye/face protection Use approved safety glasses with side shields. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles and face shield.

Hand protection Wear protective gloves made of the following material: Butyl rubber. Viton rubber (fluoro rubber). The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material.

Other skin and body protection
Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene measures
Do not smoke in work area. Wash promptly if skin becomes contaminated. Wash hands thoroughly after handling. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. Contaminated clothing should be placed in a closed container for disposal or decontamination. Warn cleaning personnel of any hazardous properties of the product.

Respiratory protection
No specific recommendations. Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible.

Environmental exposure controls
Store in a demarcated bunded area to prevent release to drains and/or watercourses. Do not empty into drains, soil or bodies of water.

Stability and reactivity

Reactivity
There are no known reactivity hazards associated with this product.

Chemical stability
Stable at normal ambient temperatures.

Possibility of hazardous reactions
Hazardous polymerisation will not occur under normal conditions.

Conditions to avoid
No specific requirements are anticipated under normal conditions of use.

Incompatible materials / Materials to avoid
Strong oxidising agents. Acid anhydrides. Acid chlorides.

Hazardous decomposition products
Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride (HCl).

Disposal considerations

Waste treatment methods

General information
Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Do not dump into any sewers, on the ground, or into any body of water. Not to be disposed of together with household waste. Any disposal practice must be in compliance with all local and national laws and regulations. Handle and dispose contaminated packages in the same way as the product itself. Fully cured product residues are generally not regarded as hazardous waste.

Disposal methods
The product as supplied should be disposed of as hazardous waste according to European Directive 91/689/EEC.

Waste class
The waste code number applies to actual wastes depending on its origin and not to substances or mixtures as placed on the market. Only the practical application of the user enables the proper allocation. Allocation of the waste code number according to the European Waste Catalogue (Commission Decision 2000/532/EC and 2001/118/EC) should be carried out in agreement with the regional waste disposal company and/or the supervisory authority.