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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
08 June 2016 to 14 July 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
352 °C
Atm. press.:
>= 100.6 - <= 101.3 kPa

RESULTS

- Results of the auto-ignition temperature determination are shown in Table 2 (below).

- Room temperature was reported as 21 °C.

- Atmospheric pressure was reported as 100.6 to 101.3 kPa.

 

TABLE 2 – RESULTS OF THE AUTO–IGNITION TEMPERATURE DETERMINATION

Test temperature (°C)

Test weight (µL)

Ignition delay (s)

Observations

200 (clean flask)

70

> 300

No ignition. Grey fumes were emitted.

250 (clean flask)

70

> 300

No ignition. Grey fumes were emitted.

300 (clean flask)

70

> 300

No ignition. Grey fumes were emitted.

350

70

> 300

No ignition. Grey fumes were emitted.

400

70

2

An orange flame. Grey fumes were emitted.

390

70

3

An orange flame. Grey fumes were emitted.

380

70

6

An orange flame. Grey fumes were emitted.

370

70

5

An orange flame. Grey fumes were emitted.

360

70

8

An orange flame. Grey fumes were emitted.

354

70

> 300

No ignition. Grey fumes were emitted.

356 (clean flask)

70

> 300

No ignition. Grey fumes were emitted.

358 (clean flask)

70

9

An orange flame. Grey fumes were emitted.

356 (clean flask)

200

4

An orange flame. Grey fumes were emitted.

354 (clean flask)

200

6

An orange flame. Grey fumes were emitted.

352 (clean flask)

200

11

An orange flame. Grey fumes were emitted.

350 (clean flask)

200

> 300

No ignition. Grey fumes were emitted.

350 (clean flask)

400

> 300

No ignition. Grey fumes were emitted.

350 (clean flask)

600

> 300

No ignition. Grey fumes were emitted.

350 (clean flask)

800

> 300

No ignition. Grey fumes were emitted.

350 (clean flask)

1000

> 300

No ignition. Grey fumes were emitted.

Conclusions:
The test item was determined to have an auto-ignition temperature of 352 ± 5 °C.
Executive summary:

GUIDELINE

The determination was carried out using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 (30 May 2008).

RESULTS

The test item was determined to have an auto-ignition temperature of 352 ± 5 °C.

Description of key information

The test item was determined to have an auto-ignition temperature of 352 ± 5 °C (EU Method A.15).

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
352 °C

Additional information

GUIDELINE

The determination was carried out using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 (30 May 2008).

RESULTS

The test item was determined to have an auto-ignition temperature of 352 ± 5 °C.