Registration Dossier

Administrative data

First-aid measures

General advice:
Move out of dangerous area.
Never give anything by mouth to an unconscious person.

Inhalation:
Move to fresh air.

Skin contact:
Take off all contaminated clothing immediately.
If symptoms persist, call a physician.
Wash off immediately with soap and plenty of water.

Eye contact:
Protect unharmed eye.
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.

Ingestion:
Clean mouth with water and drink afterwards plenty of water.
Prevent vomiting if possible.
If a person vomits when lying on his back, place him in the recovery position.
Never give anything by mouth to an unconscious person.
If accidentally swallowed obtain immediate medical attention.

Fire-fighting measures

Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Extinguishing media which shall not be used for safety reasons:
High volume water jet

Specific hazards during firefighting:
Flash back possible over considerable distance.
Do not use a solid water stream as it may scatter and spread fire.
Do not allow run-off from fire fighting to enter drains or water courses.

Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus.

Further information:
In the event of fire and/or explosion do not breathe fumes.
Use water spray to cool unopened containers.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Accidental release measures

Personal precautions:
Ensure adequate ventilation.
Use personal protective equipment.
Keep people away from and upwind of spill/leak.
Remove all sources of ignition.

Environmental precautions:
Should not be released into the environment.
Avoid subsoil penetration.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up:
Dam up.
Wipe up with absorbent material (e.g. cloth, fleece).

Additional advice:
Local authorities should be advised if significant spillages cannot be contained.
Suppress (knock down) gases/vapours/mists with a water spray jet.

Handling and storage

Advice on safe handling:
Wear personal protective equipment.
Dispose of rinse water in accordance with local and national regulations.
Avoid contact with skin and eyes.
Use personal protective equipment.

Advice on protection against fire and explosion:
Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).
Use explosion-proof equipment.
Avoid formation of aerosol.
Do not spray on a naked flame or any incandescent material.
When using do not smoke.
Keep away from open flames, hot surfaces and sources of ignition.

Requirements for storage areas and containers:
Store in original container.
Keep container tightly closed in a dry and well-ventilated place.
To maintain product quality, do not store in heat or direct sunlight.
No smoking.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Advice on common storage:
No special restrictions on storage with other products.

Other data:
No decomposition if stored and applied as directed.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each manufacturing site.

Transport information

Land transport (ADR/RID)

UN number:
1988
Shippingopen allclose all
Class:
3
Classification code:
FT1
Packaging group:
III
Labels:
3
6.1
Environmentally Hazardous Substance mark
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1988
Shippingopen allclose all
Class:
3
Classification code:
FT1
Packaging group:
III
Labels:
3
6.1
Environmentally Hazardous Substance mark
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1988
Proper shipping name and description:
Aldehydes, flammable, toxic, n.o.s.
Chemical name:
TRANS-2-HEXENAL,TRANS-2-HEXENOIC ACID
Class:
3
Packaging group:
III
EmS code:
F-E, S-D
Labels:
3
6.1
Environmentally Hazardous Substance mark
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1988
Proper shipping name and description:
Aldehydes, flammable, toxic, n.o.s.
Chemical name:
TRANS-2-HEXENAL,TRANS-2-HEXENOIC ACID
Class:
3
Packaging group:
III
Labels:
3
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Respiratory protection:
No personal respiratory protective equipment normally required.

Hand protection:
Wear chemicals-resistant gloves, e.g. safety gloves of chloroprene Level 2 or of butyl rubber Level 6.

Eye protection:
Safety glasses

Skin and body protection:
Lightweight protective clothing
Remove and wash contaminated clothing before re-use.

Hygiene measures:
Avoid contact with skin, eyes and clothing.
Wash hands before breaks and immediately after handling the product.

Protective measures:
When using, do not eat, drink or smoke.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each manufacturing site.

Stability and reactivity

No dangerous reaction known under conditions of normal use.

Disposal considerations

Product:
Where possible recycling is preferred to disposal or incineration.
If recycling is not practicable, dispose of in compliance with local regulations.

Contaminated packaging:
Empty remaining contents.
Dispose of as unused product.