Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
General information
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

After inhalation
In case of accident by inhalation: remove casualty to fresh air and keep at rest. In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks). In case of allergic symptoms, especially in the breathing area, seek medical advice immediately.

After contact with skin
Remove contaminated, saturated clothing immediately. After contact with skin, wash immediately with: Water. In case of skin irritation, seek medical treatment.

After contact with eyes
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist.

After ingestion
Rinse mouth thoroughly with water. Call a physician immediately. Let water be drunken in little sips (dilution effect).

4.2. Most important symptoms and effects, both acute and delayed
No information available.

4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media
Water spray.
alcohol resistant foam.
dry extinguishing powder.
The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.

Unsuitable extinguishing media
High power water jet.

5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2).

5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.

Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Safe handling: see section Handling and storage
Personal protection equipment: see section Exposure controls/ personal protection

6.2. Environmental precautions
Do not allow to enter into surface water or drains. Prevent spread over a wide area (e.g. by containment or oil barriers).

6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal.
Clean contaminated objects and areas thoroughly observing environmental regulations.

Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Wear suitable protective clothing. (See section Exposure controls/ personal protection)
Use extractor hood (laboratory).

Advice on protection against fire and explosion
Usual measures for fire prevention

Further information on handling
Avoid contact with skin, eyes and clothes.


7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage rooms and vessels
Keep container tightly closed in a cool, well-ventilated place.

Hints on joint storage
Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious substances. Food and animal feedingstuff.

Further information on storage conditions
Keep the packing dry and well sealed to prevent contamination and absorbtion of humidity.
Recommended storage temperature: 20°C
Protect against: Light. UV-radiation/sunlight. heat. moisture.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
No dangerous good in sense of this transport regulation.
Shippingopen allclose all
Labels:
No dangerous good in sense of this transport regulation.
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
No dangerous good in sense of this transport regulation.
Shippingopen allclose all
Labels:
No dangerous good in sense of this transport regulation.
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
No dangerous good in sense of this transport regulation.
Shipping information
Proper shipping name and description:
No dangerous good in sense of this transport regulation.
Chemical name:
No dangerous good in sense of this transport regulation.
Labels:
No dangerous good in sense of this transport regulation.
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
No dangerous good in sense of this transport regulation.
Shipping information
Proper shipping name and description:
No dangerous good in sense of this transport regulation.
Chemical name:
No dangerous good in sense of this transport regulation.
Labels:
No dangerous good in sense of this transport regulation.
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters
Exposure limits (EH40)
CAS No Substance ppm mg/m3 Category Origin
98-01-1 2-Furaldehyde (furfural) 2 8 TWA (8 h) WEL
5 20 STEL (15 min) WEL
50-00-0 Formaldehyde 2 2.5 TWA (8 h) WEL
2 2.5 STEL (15 min) WEL
Additional advice on limit values
To date, no national critical limit values exist.

8.2. Exposure controls
Appropriate engineering controls
Provide adequate ventilation.

Protective and hygiene measures
Always close containers tightly after the removal of product. When using do not eat, drink, smoke, sniff. Wash hands before breaks and after work.

Eye/face protection
Wear safety glasses; chemical goggles (if splashing is possible). DIN EN 166

Hand protection
Wear suitable gloves.
Suitable material:
FKM (fluororubber). - Thickness of glove material: 0,4 mm
Breakthrough time >= 8 h
Butyl rubber. - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
CR (polychloroprenes, Chloroprene rubber). - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
NBR (Nitrile rubber). - Thickness of glove material: 0,35 mm
Breakthrough time >= 8 h
PVC (Polyvinyl chloride). - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Check leak tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well.

Skin protection
Suitable protective clothing: Lab apron.
Minimum standard for preventive measures while handling with working materials are specified in the TRGS 500 (D).

Respiratory protection
With correct and proper use, and under normal conditions, breathing protection is not required.
Respiratory protection necessary at:
-exceeding exposure limit values
-insufficient ventilation and aerosol or mist formation
Suitable respiratory protective equipment: particulates filter device (DIN EN 143). Type: P1-3 The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190).

Environmental exposure controls
No special precautionary measures are necessary.

Stability and reactivity

10.1. Reactivity
No information available.

10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.

10.3. Possibility of hazardous reactions
No information available.

10.4. Conditions to avoid
Protect against: UV-radiation/sunlight. heat.

10.5. Incompatible materials
Materials to avoid: Oxidizing agents, strong. Reducing agents, strong.

10.6. Hazardous decomposition products
Can be released in case of fire: Carbon dioxide (CO2). Carbon monoxide

Disposal considerations

13.1. Waste treatment methods
Advice on disposal
Observe in addition any national regulations! Consult the local waste disposal expert about waste disposal. Non-contaminated packages may be recycled. According to EAKV, allocation of waste identity numbers/waste descriptions must be carried out in a specific way for every industry and process. Control report for waste code/ waste marking according to EAKV:

Waste disposal number of waste from residues/unused products
160305 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; off-specification batches and unused products; organic wastes containing hazardous substances; hazardous waste

Waste disposal number of used product
160305 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; off-specification batches and unused products; organic wastes containing hazardous substances; hazardous waste

Waste disposal number of contaminated packaging
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by hazardous substances; hazardous waste

Contaminated packaging
Handle contaminated packages in the same way as the substance itself.